A Solvothermal Synthesis and Characterization of a New Compound (PyH)[Cu2(ttc)]  

作　　者：李飞 刘艳 张仁春 纪敏 安永林 

机构地区：[1]School of Chemistry, Dalian University of Technology [2]Key Laboratory of New Optoelectronic Functional Materials(Henan Province), College of Chemistry and Chemical Engineering, Anyang Normal University

出　　处：《Chinese Journal of Structural Chemistry》2018年第12期1979-1986,1846,共9页结构化学（英文）

基　　金：supported by National Natural Science Foundation of China(21770643)

摘　　要：One two-dimensional compound(PyH)[Cu(ttc)](PyH = protonated pyridine) was solvothermally synthesized in the presence of thiophenol mineralizer using ttcH3(1,3,5-triazine-2,4,6-trithione, trithiocyanuric acid) ligand. It crystallizes in the triclinic system, space group P1 with a = 7.6824(12), b = 7.8094(13), c = 9.9541(18) ?, V = 555.95(16) ?~3, Z = 2, T = 296(2) K, GOOF = 1.136, λ(Mo Kα) = 0.71073 ?, D3c = 4.555 g/cm, CuSNCH, Mr = 382, F(000) = 737, the final R = 0.0654, wR = 0.1936 for 1558 observed reflections with I > 2s(I). Structure analyses indicate that the whole Cu(I) atoms have planar triangular coordination. The compound shows intense fluorescent emission and high thermal stability.One two-dimensional compound(PyH)[Cu_2(ttc)](PyH = protonated pyridine) was solvothermally synthesized in the presence of thiophenol mineralizer using ttcH3(1,3,5-triazine-2,4,6-trithione, trithiocyanuric acid) ligand. It crystallizes in the triclinic system, space group P1 with a = 7.6824(12), b = 7.8094(13), c = 9.9541(18) ?, V = 555.95(16) ?~3, Z = 2, T = 296(2) K, GOOF = 1.136, λ(Mo Kα) = 0.71073 ?, D3c = 4.555 g/cm, Cu_2S_3N_4C_8H_6, Mr = 382, F(000) = 737, the final R = 0.0654, wR = 0.1936 for 1558 observed reflections with I > 2s(I). Structure analyses indicate that the whole Cu(I) atoms have planar triangular coordination. The compound shows intense fluorescent emission and high thermal stability.

关 键 词：solvothermal synthesis 1 3 5-triazine-2 4 6-trithione MINERALIZER 

分 类 号：TQ[化学工程]