环钯化合物合成及其在催化中的应用  

Syntheses and Catalytic Applications of Palladacycles Complexes

作　　者：胡子乔 刘贵传[1] 孔勇[1] 林永学[1] 金军斌[1] Hu Ziqiao;Liu Guichuan;Kong Yong;Lin Yongxue;Jin Junbin(Research Institute of Petroleum Engineering,SINOPEC,Beijing 100101)

机构地区：[1]中国石化石油工程技术研究院,北京100101

出　　处：《化学通报》2019年第1期32-36,共5页Chemistry

基　　金：国家科技重大专项(2016ZX05021004-002);中石化科技部项目(P18001-2;P17002-8)资助

摘　　要：环钯化合物由于丰富的结构、高度的稳定性和卓越的催化性能,已成为钯化学研究的热点之一。迄今已开发出了C-H键活化、氧化加成、转金属化、亲核加成和配体交换等多种方法,可制备出从三元环到十一元环的CY型环钯化合物和多种YCY型环钯化合物。环钯化合物目前已应用于偶联、烯烃氢化和不对称催化等反应中。本文简单介绍了环钯化合物的种类,重点介绍了环钯化合物的合成方法和催化应用情况,最后提出了环钯化合物在今后合成研究和催化应用中的发展建议。Due to their abundant structures,high stability and excellent catalytic properties,palladacycles complexes have become one of the hotspots in the research of palladium chemistry. A number of synthesis methods have been developed,such as C-H bond activation,oxidation addition,metal transfer,nucleophilic addition,and ligand exchange. The CY type palladacycles complexes from ternary ring to eleven-membered ring and YCY type palladacycles complexes have been afforded. Palladacycles complexes have been utilized in olefin hydrogenation,coupling reaction,asymmetric catalysis,and other reactions. In this article,the types of palladacycles complexes were briefly introduced. The synthesis methods and application for catalytic reactions of palladacycles complexes were focused on. The development suggestions of palladacycles complexes for synthesis and catalytic application were proposed.

关 键 词：环钯化合物 合成 催化 

分 类 号：O643.36[理学—物理化学]