Recent progress on the frontiers of polyoxometalates structures and applications  

作　　者：Sai An Jian-Cai Liu Huaiying Zhang Lifu Wu Bo Qi Yu-Fei Song 

机构地区：[1]State Key Laboratory of Chemical Resource Engineering, Beijing Advanced Innovation Center for Soft Matter Science and Engineering,Beijing University of Chemical Technology

出　　处：《Science China Chemistry》2019年第2期159-161,共3页中国科学（化学英文版）

基　　金：supported by the National Key Research and Development Program of China (2017YFB0307303);the National Natural Science Foundation of China (U1707603, 21625101, 21521005, U1507102, 201808011);the National Basic Research Program of China (2014CB932104);Beijing Natural Science Foundation (2182047);Postdoctoral Science Foundation of China (2018M631313);the Fundamental Research Funds for the Central Universities (ZY1709)

摘　　要：Polyoxometalates (POMs),a class of discrete anionic metal oxides in groups V and VI,are constructed via the con- densation of metal oxide polyhedral (MOx,M=W^vI,Mo^vI, Vv,Nb,Ta,etc.and x=4-7)with each other in a comer-, edge-,or rarely in a face-sharing manner [1-3].Up to now, the broadening family of POM derivatives ranges from small size clusters to nanoscale giant aggregates,which have shown impressive chemical and physical properties and great potential in fields of catalysis,magnetism,medicine,photochemistry,environment,energy and materials science [4,5].Latest progress on POMs chemistry is directed to the construction of high-nnclearity clusters and the exploration of functional applications in energy chemistry,catalysis,and self-assembly (Figure 1).

关 键 词：POLYOXOMETALATES DISCRETE METAL OXIDES 

分 类 号：O6[理学—化学]