乙二胺四乙酸添加量对三维棒花状钒酸铋形貌及光催化活性的影响  

Influence of Ethylene Damine Tetraacetic Acid Surfactant on 3D Rodflower-like Morphology and Photocatalytic Performance of BiVO4 Powders

作　　者：郭鹏瑶 王敏[2] 胡筱敏[1] 孙明志[1] GUO Pengyao;WANG Min;HU Xiaomin;SUN Mingzhi(School of Resources and Civil Engineering,Northeastern University,Shenyang 110819,China;School of Mechanical Engineering and Automation Northeastern University,Shenyang 110819,China)

机构地区：[1]东北大学资源与土木工程学院,沈阳110819 [2]东北大学机械工程与自动化学院,沈阳110819

出　　处：《硅酸盐学报》2018年第12期1780-1787,共8页Journal of The Chinese Ceramic Society

基　　金：国家自然科学基金青年基金(21207093)

摘　　要：以NH4VO3和Bi(NO3)3·5H2O为原料,采用乙二醇溶剂热法,通过添加乙二胺四乙酸(EDTA)制备了3D结构的棒花状BiVO4光催化剂,研究了EDTA投加量对BiVO4形貌和性能的影响,分析了合成条件下BiVO43D棒花状形貌形成的机理,以甲基橙为模拟废水,考察了其光催化活性。结果表明:添加EDTA后对样品形貌改变较大,由棒状转变为3D棒花状,且(040)、(150)、(240)、(042)、(202)晶面特征峰明显,比表面积增大、光吸收边发生红移;当EDTA添加量为0.03 g时,制备的样品对甲基橙溶液的降解率最高,50 min达到94%左右,对苯酚溶液光照120 min的降解率可达到92%左右,较未添加EDTA时显著提高。BiVO4 powders with three-dimensional(3 D) rodflower-like structure were prepared by an ethylene glycol solvent thermal method with NH4VO3 and Bi(NO3)3·5H2O as raw materials. The effect of ethylene diamine tetraacetic acid(EDTA) dosage on the morphology and properties of BiVO4 powders and the corresponding mechanism were investigated. The photocatalytic activity was evaluated via the measurement of the degradation of methyl orange(MO) solution under visible light irradiation. The results show that the EDTA has a dominat effect on the morphology. The morphology of BiVO4 can be changed from rod-like structure to 3D rod flowers-like structure after the EDTA addition. The intensity of(040),(150),(240),(042),(202) diffraction peaks increases after EDTA addition. The specific surface area increases and the optical absorption edge becomes red shift. BiVO4 prepared with the EDTA addition of 3.0 g has an optimal photocatalytic effect. The degradation rate of MO with the EDTA addition is about 94% after 50 min under visible light irradiation, and the degradation rate of phenol with the EDTA addition is around 92% after 120 min under visible light irradiation, which both are greater than those without any EDTA addition.

关 键 词：光催化 钒酸铋 溶剂法 乙二胺四乙酸 三维棒花状 

分 类 号：O643[理学—物理化学]