Gemini型双季铵盐阳离子表面活性剂的合成及应用研究进展  

Progress in Synthesis and Application of Gemini Double Quaternary Ammonium Cationic Surfactants

作　　者：张萍 臧凯[2] 袁彩彩 石贤财 章亚东[1] ZHANG Ping;ZANG Kai;YUAN Cai-cai;SHI Xian-cai;ZHANG Ya-dong(Chemical Engineering and Energy Institute,Zhengzhou University,Zhengzhou 450001,China;Jiyuan Research Institute,Zhengzhou University,Jiyuan 459000,China)

机构地区：[1]郑州大学化工与能源学院,河南郑州450001 [2]郑州大学济源研究院,河南济源459000

出　　处：《化学试剂》2019年第2期147-152,共6页Chemical Reagents

摘　　要：Gemini(双子)型双季铵盐阳离子表面活性剂以其独特的结构而具有良好的表面活性、较低的临界胶束浓度(CMC)等优良的物理性能。以间隔基团的不同综述了Gemini型双季铵盐阳离子表面活性剂的合成路线,并简要的介绍了Gemini型双季铵盐阳离子表面活性剂在杀菌、金属缓蚀、煤沥青润湿、乳化及作为基因和药物载体方面的应用,为Gemini型双季铵盐阳离子表面活性剂的后续研究提供了参考。并指出要重视其合成条件的优化,以降低生产成本,扩大Gemini型双季铵盐阳离子表面活性剂的应用范围。Gemini-type double quaternary ammonium cationic surfactant has excellent physical properties such as good surface activity and low critical micelle concentration( CMC).The synthetic routes of Gemini-type double quaternary ammonium cationic surfactant are reviewed in terms of spacer groups. Gemini-type double quaternary ammonium cationic surfactant was briefly described for sterilization,metal corrosion inhibition,and coal bitumen wetting.Emulsification and its application as a gene and drug carrier provide a reference for subsequent investigation of Gemini-type double quaternary ammonium cationic surfactant. It also pointed out that it is necessary to pay attention to the optimization of the synthesis conditions,and to reduce the production cost.It is possible to use Gemini-type double quaternary ammonium cationic surfactant in real life.

关 键 词：Gemini型双季铵盐阳离子表面活性剂 合成 应用研究 

分 类 号：TQ423.12[化学工程]