新型混凝剂聚合氯化铝钛的制备及性能表征  被引量:2

Preparation and Properties Characterization of New Coagulant Polymerization of Aluminum Chloride Titanium

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作  者:王迅 李伟[1] 刘玉灿 段晋明[1] WANG Xun;LI Wei;LIU Yucan;DUAN Jinmin(School of Environmental and Municipal Engineering,Xi'an University of Architecture and Technology,Xi'an 710055,China;School of Civil Engineering,Yantai University,Yantai 264005,China)

机构地区:[1]西安建筑科技大学环境与市政工程学院,陕西西安710055 [2]烟台大学土木工程学院,山东烟台264005

出  处:《水处理技术》2019年第2期27-31,共5页Technology of Water Treatment

基  金:陕西省教育厅专项科研基金(16JK1447);山东省自然科学基金项目(ZR2017BEE016)

摘  要:在传统聚合氯化铝(PAC)中加入钛盐制备了新型聚合氯化铝钛(PATC)混凝剂,通过ζ电位、粒径、红外和扫描电镜等表征手段与传统PAC进行了对比,并使用2种混凝剂针对西安兴庆湖原水进行了混凝实验。结果表明,经过钛盐改性的PATC的粒径和ζ电位(126.3 nm、28.29 mV)较PAC的粒径和ζ电位(16.72 nm、8.257 mV)有一定的提升,这使得其具有更高的电中和和网捕卷扫能力。同时PATC相比PAC具有更宽的pH适应范围,在整个pH范围内(5~9)均具有更强的电中和能力。在原水混凝实验中,经过钛盐改性的PATC相比于PAC,对微生物代谢产物和蛋白质类有机物的去除能力提高(去除率分别提高了6.9%与7.1%)。A new type of PATC coagulant was prepared by adding titanium salt to traditional PAC coagulant in this experiment, and compared with the traditional PAC throuth ζ potential, coagulant size, FI TR and SEM, etc. At the same time, the raw water coagulation experiments by two kinds of coagulant were also conducted. The results showed that the titanium salt modified PATC had larger particle size and zeta potential(126.3 nm, 28.29 mV) than PAC(16.72 nm, 8.257 mV), which makes it had higher electric neutralization and sweep capacity. In addition, PATC had a wider effective range of pH than PAC, and had stronger electric neutralization ability throughout the entire pH range(5~9). In the raw water coagulation experiments, the titanium saltmodified PATC increased the removal efficiency of microbial metabolites and protein-liked organic matters compared with PAC, the removal rate increased by 6.9% and 7.1% respectively.

关 键 词:聚合氯化铝钛 聚合氯化铝 混凝 电中和作用 网捕作用 

分 类 号:TU991.22[建筑科学—市政工程]

 

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