绿色溶剂中苯乙烯-马来酸酐无规共聚物的合成及表征  

Synthesis and Characterization of Styrene-Maleic Anhydride Random Copolymer in Green Solvent

作　　者：石雪龙 吴剑铭 张振山 谭璞 宗成中[1] Shi Xuelong;Wu Jianming;Zhang Zhenshan;Tan Pu;Zong Chengzhong(School of Polymer Science and Engineering,Qingdao University of Science and Technology,Qingdao 266042,China)

机构地区：[1]青岛科技大学高分子科学与工程学院,山东青岛266042

出　　处：《塑料科技》2019年第2期24-28,共5页Plastics Science and Technology

摘　　要：使用绿色溶剂碳酸二甲酯(DMC)代替传统溶剂丙酮,在120℃、苯乙烯与马来酸酐配比为9:1及氮气环境下,以溶液聚合法制备了苯乙烯-马来酸酐无规共聚物(R-SMA),通过红外光谱、核磁共振、化学滴定等表征方法确证产物为R-SMA,并研究了两种溶剂及其用量对R-SMA组成、结构、分子量、转化率等的影响。结果表明:DMC作溶剂时,R-SMA以苯乙烯作为分子主链,其中SSM、MSS、MSM三种结构在分子链中随机分布,呈无规排列;随着DMC用量的增加,R-SMA的分子量降低,转化率先升高后降低,马来酸酐含量变化不大;与丙酮作溶剂相比,DMC作溶剂时,产物的分子量及马来酸酐含量均较低,耐热性更好。The random copolymer of styrene-maleic anhydride(R-SMA) was prepared by solution copolymerization with dimethyl carbonate(DMC) as a green solvent instead of acetone at 120℃, the ratio of styrene to maleic anhydride was 9:1 and nitrogen atmosphere. The product was confirmed to be R-SMA by IR, NMR and chemical titration. The effects of two solvents and their dosage on the composition, structure, molecular weight and conversion of R-SMA were studied. The results show that when DMC is used as solvent, R-SMA takes styrene as its main molecular chain. The three structures of SSM, MSS and MSM are randomly distributed in the molecular chain and arranged randomly. With the increase of DMC dosage, the molecular weight of R-SMA decreases, the conversion rate increases first and then decreases, and the content of maleic anhydride does not change much. Compared with acetone, the molecular weight and maleic anhydride content of the product are lower and the heat resistance is better when DMC is used as solvent.

关 键 词：绿色溶剂 碳酸二甲酯 苯乙烯-马来酸酐无规共聚物 

分 类 号：TQ325.2[化学工程—合成树脂塑料工业]