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作 者:QIAN Miaomiao SUI Jiayang WANG Xiaofeng ZHU Yanchao
机构地区:[1]College of Chemistry,Jilin University,Changchun 130012,P.R.China [2]Institute for Frontier Materials,Deakin University,Geelong VIC 3216,Australia
出 处:《Chemical Research in Chinese Universities》2019年第1期139-145,共7页高等学校化学研究(英文版)
摘 要:A pyrolyzed ash containing about 50% carbon,named silicon carbon black(SiCB),was prepared by the anoxic pyrolysis of rice husk.Fourier transform infrared spectroscopy(FTIR),thermogravimetric analysis(TGA), Brunauer-Enunett-Teller(BET),transmission electron microscopy(TEM)and universal material testing machine were used to analyze the stress-strain relationship,Mullins effect and static viscoelastic properties of SiCB-filled vulcanized natural rubber(NR),and SiCB was compared with a commercially available semi-reinforcing fumace(SRF) carbon black.The results show that the vulcanized natural rubber filled with SiCB had similar reinforcing properties to those of that filled with traditional SRF,but obvious differences between them exist in stress-strain properties and stress softening resistance.We tried to discuss the related phenomena with the aid of the modified two-layer theory. And it is successfully predicted and verified that SiCB has good compression resistance and obvious stress relaxation advantages in compression stress relaxation.
关 键 词:SILICON carbon black Natural rubber STRESS-STRAIN relationship Stress RELAXATION
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