无隔膜电解槽中对苯醌电合成的研究  

Studies on Electrosynthesis of Para Quinone in an Undivided Electrolytic Cell

作　　者：赵玉娥[1] 张恒彬[2] 孙家锺[3] 

机构地区：[1]北京联合大学化学工程学院,北京100023 [2]吉林大学化学科学学院,长春130023 [3]吉林大学理论化学研究所,长春130023

出　　处：《吉林大学学报（理学版）》2002年第2期215-217,共3页Journal of Jilin University:Science Edition

摘　　要：在无隔膜电解槽中 ,以 Cu2 +离子为电解媒质 ,铜板作阳极 ,石墨作阴极 ,对苯的间接电氧化进行研究 .实验结果表明 。In an undivided electrolytic cell and with benzene as the starting material, Cu 2+ ions as electrolytic medium, Cu as the anode material and graphite as the cathode material, the synthesis of para quinone via the indirect electrooxidation of benzene was studied. The experimental results demonstrate that the yield of electrolytic products para quinone and current efficiency were higher than the corresponding ones for direct electrooxidation of benzene in the divided electrolytic cell.

关 键 词：对苯醌 间接电氧化 无隔膜电解槽 电合成 电解媒质 电流效率 铜离子 

分 类 号：O623.312[理学—有机化学] O621.38[理学—化学]