含溴芳基磷酸三聚氰胺盐的合成及应用  

Synthesis and Application of Phosphorus-Bromine-Nitrogen Containing Flame Retardant

作　　者：刘治国[1] 丁涛[1] 贾修伟[1] 王素敏[1] 王彦林[1] 

机构地区：[1]河南大学化学化工学院,河南开封475001

出　　处：《河南大学学报（自然科学版）》2002年第1期33-36,共4页Journal of Henan University:Natural Science

基　　金：河南省教育厅自然基金项目 (0 0 15 0 0 2 6 )

摘　　要：以三氯氧磷、2 ,4,6 -三溴苯酚及三聚氰胺等为原料合成了含磷 -溴 -氮阻燃剂O - (2 ,4,6 -三溴苯基 )磷酸三聚氰胺盐 (Ⅲ )和O ,O -二 (2 ,4,6 -三溴苯基 )磷酸三聚氰胺盐 (Ⅳ ) ,元素分析、红外光谱、1HNMR等确定了结构 .在不饱和聚酯树脂中应用试验证明磷 -溴 -氮在同一分子中具有协同阻燃作用 ,相同添加量时阻燃剂 (Ⅲ )、(Ⅳ )的阻燃性能优于含磷 -溴阻燃剂 (Ⅴ ) .应用试验表明 ,阻燃剂 (Ⅲ )、(Ⅳ )、(Ⅴ )phosphorus_bromine_nitrogen containing flame retardant O_(2,4,6_tribromophenyl) phosphoric melamine salt(Ⅲ) and O,O_di(2,4,6_Tribromophenyl)phosphoric salt (Ⅳ) were synthesized, with their structures confirmed by elemental analyses, FT_IR etc. It showed that phosphorus_bromine_nitrogen in same molecular had synergism. Simultaneously, it was confirmed that phosphorus_bromine_nitrogen containing compounds (Ⅲ) and (Ⅳ) were superior to phosphorus_bromine containing flame retardant (Ⅴ). The application test showed that the flame retardants (Ⅲ),(Ⅳ) and (Ⅴ) could not influence the physics mechanical property of unsaturated polyester resin.

关 键 词：阻燃剂 磷-溴-氮协同作用 0-(2 4 6-三溴苯基)磷酸三苯氰胺盐 O O-二(2 4 6-三溴苯基)磷酸盐 合成 阻燃性能 应用 

分 类 号：TQ314.248[化学工程—高聚物工业] O633.4[理学—高分子化学]