相转移催化合成硫氰酸铵  

Synthesis of Ammonium Thiocyanate by Phase Transfer Catalysis

作　　者：庞秀言[1] 孙汉文[1] 李志远[1] 张红娟[1] 

机构地区：[1]河北大学化学与环境科学学院,保定071002

出　　处：《应用化学》2002年第4期407-408,共2页Chinese Journal of Applied Chemistry

摘　　要：Ammonium thiocyanate was prepared in 2 steps from aqueous ammonia and carbon disulfied by phase transfer catalysis in yield of 72 7%, when catalysts consisted of OP 4 and OP 21 in mole ratio of 4∶6. The effects of reaction temperature, time, mole ratio of OP 4 to OP 21 and conparison with other catalysts on the reaction were descurved.Ammonium thiocyanate was prepared in 2 steps from aqueous ammonia and carbon disulfied by phase transfer catalysis in yield of 72 7%, when catalysts consisted of OP 4 and OP 21 in mole ratio of 4∶6. The effects of reaction temperature, time, mole ratio of OP 4 to OP 21 and conparison with other catalysts on the reaction were descurved.

关 键 词：硫氰酸铵 相转移催化反应 合成 催化剂 OP-4 OP-21 

分 类 号：O614.61[理学—无机化学] O643.32[理学—化学]