具有平面结构的四齿肼基硫代甲酸苄酯席夫碱镍配合物的合成,晶体结构和三阶非线性光学性质研究(英文)  

Synthesis, Structure and Third-Order Nonlinear Optical Properties of a Planar Nickel Complex with Rigid Quadridentate Schiff Base Derived from S-benzyl Dithiocarbazate

作　　者：周建豪[1] 王玉晓[2] 陈学太[1] 宋瑛林[2] 翁林红[3] 游效曾[1] 

机构地区：[1]南京大学配位化学国家重点实验室配位化学研究所,南京210093 [2]哈尔滨工业大学应用物理系,哈尔滨150001 [3]复旦大学化学系,上海200433

出　　处：《无机化学学报》2002年第5期533-536,共4页Chinese Journal of Inorganic Chemistry

基　　金：国家自然科学基金资助项目(No.20028101);江苏省自然科学基金资助项目(No.BK99032)~~

摘　　要：A planar metal complex NiL, H2L=acenaphthenequinone bis(S benzyldithiocarbazate), 1, has been prepared via the template effect of nickel ion. Crystal structure of 1 was determined by X ray diffraction analysis and shows the planar coordination configuration around the central nickel atom. Z scan measurements show that 1 is a transition metal complex exhibiting high third order nonlinear optical effect.A planar metal complex NiL, H2L=acenaphthenequinone bis(S benzyldithiocarbazate), 1, has been prepared via the template effect of nickel ion. Crystal structure of 1 was determined by X ray diffraction analysis and shows the planar coordination configuration around the central nickel atom. Z scan measurements show that 1 is a transition metal complex exhibiting high third order nonlinear optical effect.

关 键 词：镍 平面结构 晶体结构 三阶线性光学 四齿肼基硫代甲酸苄酯 席夫碱 配合物 合成 

分 类 号：O614.813[理学—无机化学]