二茂铁乙酮-2,4-二硝基苯腙的合成及表征  

Synthesis and characterization of acetyl ferrocene-2,4-dinitrophenyl hydrazone

作　　者：吴之传[1] 姚海波[1] 司鹏[1] 

机构地区：[1]安徽机电学院生化工程系,芜湖241000

出　　处：《化学试剂》2002年第2期95-96,共2页Chemical Reagents

摘　　要：以二茂铁与乙酸酐在磷酸催化下反应 ,合成出乙酰基二茂铁 ,再用乙酰基二茂铁与 - 2 ,4 -二硝基苯肼作用 ,得到化合物二茂铁乙酮 - 2 ,4 -二硝基苯腙。通过多步实验确定出最佳合成条件 ,并通过元素分析、质谱。Acetyl ferrocene was synthesized by acetylation of ferrocene with acetic anhydride.Further reaction of acetyl ferrocene with 2,4 dinitrophenyl hydrazine gave new compound acetyl ferrocene 2,4 dinitrophenyl hydrazone,the structure of it was characterized by elementary analysis,IR and MS.The reaction conditions were studied.

关 键 词：二茂铁乙酮-2 4-二硝基苯腙 二茂铁 合成 表征 乙酸酐 

分 类 号：O627.81[理学—有机化学]