混杂配体金属簇合物的分子振动光谱与结构  

Spectra and Structure of the Metal Cluster Complexes with Mixed Ligands

作　　者：陈瑞平[1] 郑瑜[1] 龙德良[1] 黄锦顺[1] 

机构地区：[1]结构化学国家重点实验室,中国科学院福建物质结构研究所,福建福州350002

出　　处：《光谱学与光谱分析》2002年第2期254-256,共3页Spectroscopy and Spectral Analysis

基　　金：国家自然科学基金资助

摘　　要：由于原子簇化合物在催化 ,生物活性 ,功能材料等方面所呈现的重要性 ,使其成为无机和物理化学最重要的研究领域之一。文章中用谱学方法对一些具有混配体的过渡金属簇合物的结构及其两者之间的关系进行研究。The cluster compounds become one of the most important fields in inorganic chemistry and physical chemistry study becasuse of their character and potential use in catalyzer., functional material, etc. The IR and Raman spectra of the crystals with two different ligands, one is easily deoxidized and the other is easily oxidized, have been investigated, and the relationship between the spectrum and the structure has been discussed as well.

关 键 词：混杂配体 金属簇合物 分子振动光谱 结构 外红光谱 拉曼光谱 电荷跃迁 

分 类 号：O641.4[理学—物理化学] O561.3[理学—化学]