含羧基侧基的聚芳醚酮树脂的合成与表征(Ⅱ)  

The Synthesis and Study of Polyaromatic Ether Ketone Ketone Containing Carboxy on Side Chain (Ⅱ)

作　　者：程彩霞[1] 宋才生[1] 

机构地区：[1]江西师范大学化学与生物科学学院,江西南昌330027

出　　处：《江西师范大学学报（自然科学版）》2002年第2期98-101,共4页Journal of Jiangxi Normal University(Natural Science Edition)

基　　金：江西省自然科学基金资助项目 (0 0 110 9)

摘　　要：以 1,2 ,4-苯三甲酰氯 (TMAC)、对苯二甲酰氯 (TPC)和二苯醚 (DPE)为单体 ,通过亲电缩聚反应合成了系列含羧基侧基的聚芳醚酮酮共聚物 ,并用IR、DSC、WAXD等方法对其进行了分析表征 .结果表明 :TMAC摩尔含量小于 30 %时可制得结晶聚合物 .随着主链中TMAC含量的增加 ,共聚物的Tg、Tm、结晶度逐渐下降 。A series of novel poly (aryl ether ketone ketone ) containing carboxy on side chain was synthesized from TMAC, TPC and DPE by friedel-crafts electrophilic polymerization in a catalyst /solvent system of aluminium chloride /1,2-dichloro ethane and NMP.The prepared copolymers were characterized by IR,X-Ray,DSC,etc.The results show that the copolymers are made when the TMAC content was below 30%.The copolymers exhibit better heat-resistance .The T g,T m and crystallinity of copolymers decrease with TMAC content increasing.The copolymers still have excellent solvent-resistance.

关 键 词：羧基侧基 聚芳醚酮树脂 合成 表征 共聚物 1 2 4-苯甲酰氯 亲电缩聚反应 结晶度 

分 类 号：O632.4[理学—高分子化学]