一种改进方法合成六(4-硝基酚氧)环三磷腈  

Synthesis of Hexakis(4-nitrophenoxy)cyclotriphosphazene by an Improved Method

作　　者：吴祥雯[1] 房昌水[1] 王民[1] 王卓[1] 潘奇伟[1] 顾庆天[1] 

机构地区：[1]山东大学晶体材料国家重点实验室,济南250100

出　　处：《化学学报》2002年第5期955-956,共2页Acta Chimica Sinica

基　　金：国家自然科学基金 (No .6 9990 5 40 )资助项目

摘　　要：报道合成六 (4 硝基酚氧 )环三磷腈的一种改进方法 ,该法大大缩短了反应时间 (约 1.5h) ,简化了操作 .产物经红外、核磁氢谱和磷谱的分析。An improved method to synthesize hexakis (4-nitrophenoxy) cyclotriphosphazene is reported. The reaction time (only about 1.5 h) is much shorter by this method than by other methods reported and the operation is also simplified. The product is characterized by IR, H-1 NMR, P-31 NMR spectra, elemental analysis and DSC (differential scanning calorimetry).

关 键 词：六(4-硝基酚氧)环三磷腈 合成 环状磷腈化合物 

分 类 号：O624[理学—有机化学]