配合物[Mn(C_(13)H_8N_2OBr)_2(C_5H_5N)_2]·3C_5H_5N的结构与磁性研究  

Study on Crystal Structure and Magnetic Susceptibility of [Mn(C_(13)H_8N_2OBr)_2(C_5H_5N)_2]·3C_5H_5N

作　　者：李君[1] 张逢星[1] 史启祯[1] 

机构地区：[1]西北大学化学系,陕西省物理无机化学重点实验室,西安710069

出　　处：《无机化学学报》2002年第6期643-645,共3页Chinese Journal of Inorganic Chemistry

基　　金：8陕西省教委专项基金资助课题(No.01JK078);陕西省教委专项基金资助课题(No.01JK078)。

摘　　要：The complexMn ￡¨C ￡±￡3 H ￡? N￡2OBr ￡(c)￡2￡¨C￡μH￡μN￡(c)2·3C5H5 N has been synthesized and characterized by X-Ray diffraction,IR and variable temperature(?10to ?￡2￡*￡?K￡(c)magnetic susceptibility￡(r)X-Ray dif fraction result for the single crystal shows that the crysta l belongs to monoclinic,space group P21￡ˉc￡?a￡1/2￡±￡(r)￡°￡1￡?￡1￡¨￡3￡(c)nm￡?b￡1/2￡2￡(r)￡°￡1￡°￡3￡¨￡μ￡(c)nm￡?c￡1/2￡2￡(r)￡°￡′￡?￡±￡¨￡?￡(c)nm￡?|?￡1/2￡1￡*￡(r)￡3￡?￡?￡¨￡?￡(c)￡?V￡1/2￡′￡(r)6&獭?￡¨￡2￡(c)nm￡3￡?Z ￡1/2￡′￡?Dc￡1/2￡±￡(r)47g·cm-3 。The complexMn ￡¨C ￡±￡3 H ￡? N￡2OBr ￡(c)￡2￡¨C￡μH￡μN￡(c)2·3C5H5 N has been synthesized and characterized by X-Ray diffraction,IR and variable temperature(?10to ?￡2￡*￡?K￡(c)magnetic susceptibility￡(r)X-Ray dif fraction result for the single crystal shows that the crysta l belongs to monoclinic,space group P21￡ˉc￡?a￡1/2￡±￡(r)￡°￡1￡?￡1￡¨￡3￡(c)nm￡?b￡1/2￡2￡(r)￡°￡1￡°￡3￡¨￡μ￡(c)nm￡?c￡1/2￡2￡(r)￡°￡′￡?￡±￡¨￡?￡(c)nm￡?|?￡1/2￡1￡*￡(r)￡3￡?￡?￡¨￡?￡(c)￡?V￡1/2￡′￡(r)6&獭?￡¨￡2￡(c)nm￡3￡?Z ￡1/2￡′￡?Dc￡1/2￡±￡(r)47g·cm-3 。

关 键 词：锰配合物 SCHIFF碱 晶体结构 合成 磁性能 锰酶 模拟酶 

分 类 号：Q55[生物学—生物化学] O614.711[理学—无机化学]