HPMαFP与1,10-菲罗啉(Phen)等中性萃取剂对Co(Ⅱ)协同萃取的性能研究  

Synergistic Extraction of Co(Ⅱ) with Furoylpyrazolone And Some Neutral Donors

作　　者：蒋礼[1] 李锦州[1] 曹晶[1] 闫天宇[1] 

机构地区：[1]哈尔滨师范大学化学系,黑龙江哈尔滨150080

出　　处：《化学与粘合》2002年第3期117-119,共3页Chemistry and Adhesion

摘　　要：对在氯仿溶液中用 1 -苯基 - 3 -甲基 - 4 - (α-呋喃甲酰基 )吡唑啉酮 - 5 (HPMαFP)对Co(Ⅱ )的萃取性能进行了研究。结果表明 ,HPMαFP的萃取效果随其浓度的增大而显著增加 ,还研究了HPMαFP与 1 ,1 0 -邻菲罗啉 (Phen)、三辛基氧膦(TOPO)、二苯亚砜 (DPSO)、2 ,2′ -联吡淀 (DIPY)的氯仿溶液对Co(Ⅱ )的协同萃取 ,结果是HPMαFP与Phen的协萃作用显著 ,与DIPY协萃作用较小 ,与TOPO、DPSO无协萃效应 ;还根据模拟萃合物Co(PMαFP) 2 和Co(PMαFP) 2 ·Phen的红外光谱和元素分析结果 。The extraction of Co(Ⅱ) with 1-pheny1-3-methy1-4-(α-furoyl)-pyrazolone-5(HPMαFP) in chloroform solution was studied.The results showed that the extracted ability of HPMαFP increased obviously with the increase of its concentration.At the same time,the synergistic extraction of Co(Ⅱ) with HPMαFP and some neutral donors,1,10-phenanthroline (Phen),dipyridine(DIPY),triotylphosphine oxide(TOPO) and dipheylsulfoxide(DPSO) in chloroform solution was also.It was found that the that the effect of Phen is very apparent and that of DIPY is less,but the effects of TOPO and DPSO were not found out in the chart of synergistic extraction.The composition of extraction was discussed according to IR and element analysis of the simulative extracted complexes.

关 键 词：HPMαFP 1 10-菲罗啉 中性萃取剂 Co(Ⅱ) 协同萃取 钴(Ⅱ) 

分 类 号：O614.812[理学—无机化学] O652.62[理学—化学]