新型三维H_(0.5)CoP_(0.5)O_(2.5)的水热合成与结构表征  

Hydrothermal Synthesis and Crystal Structure of a Novel 3-D Compound [H_(0.5)CoP_(0.5)O_(2.5) ]

作　　者：李传碧[1] 徐吉庆[1] 曾庆新[1] 苏畅[1] 张丽娟[1] 叶铃[2] 

机构地区：[1]吉林大学化学学院 [2]吉林大学超分子结构与光谱实验室,长春130023

出　　处：《高等学校化学学报》2002年第6期1002-1003,共2页Chemical Journal of Chinese Universities

基　　金：国家自然科学基金 (批准号 :2 973 3 0 90 );高等学校博士学科点专项基金资助

摘　　要：A novel 3 D compound, [H 0.5 CoP 0.5 O 2.5 ], was hydrothermally synthesized and structurally characterized by singly crystal X ray diffraction, ICP, elemental analysis and IR spectra. The compound crystallizes in orthorhombic system, space group Pnnm with a =0.805 1(2) nm, b =0.838 09(13) nm, \{ c =\}0.595 0(2) nm, V =0.401(2) nm 3, Z=1, D =1.669 Mg/cm 3, R=0.049 1, wR =0.153 2.A novel 3 D compound, [H 0.5 CoP 0.5 O 2.5 ], was hydrothermally synthesized and structurally characterized by singly crystal X ray diffraction, ICP, elemental analysis and IR spectra. The compound crystallizes in orthorhombic system, space group Pnnm with a =0.805 1(2) nm, b =0.838 09(13) nm, \{ c =\}0.595 0(2) nm, V =0.401(2) nm 3, Z=1, D =1.669 Mg/cm 3, R=0.049 1, wR =0.153 2.

关 键 词：H0.5CoP0.5O2.5 水热合成 三维化合物 晶体结构 磷酸钴盐 分子筛 

分 类 号：TQ424.25[化学工程] TQ426.6