两个β-二酮Co(Ⅱ)配合物[Co(β-diketonate)_(2)(py)_(2)]的合成和晶体结构  

Syntheses and Crystal Structures of Twoβ-Diketonate Co(Ⅱ)Complexes,Co[(β-Diketonate)_(2)(py)_(2)]

作　　者：冯云龙[1] 

机构地区：[1]浙江师范大学化学系浙江师范大学物理化学研究所,金华321004

出　　处：《无机化学学报》2002年第7期722-725,共4页Chinese Journal of Inorganic Chemistry

摘　　要：Two Co ?complexes Co (β-diketonate) 2(py) 2Co (bzac)2 (py) 2(1)andCo (tta) 2 (py) 2(2)(bzacH =benzoylacetone,ttaH =2-thenoyltr ifluoroacetone,py =pyridine)were synthesized and characterized by X-ray diffraction.Complex1crystallizes in monoclinic system,space group P2 1 /n with a=0.7409(2),b=1.7430(4),c=1.0527(2)nm,β=102.23(3)°,V=1.3285(5)nm 3 ,Z =2,F(000)=562,D c =1.349g·cm -3 ,μ(Mo Kα)=0.684mm -1 .The structure was refined to R=0.0307and w R=0.0827for observed 2437reflectio ns with I≥2σ(I).Complex2crystallizes in triclinic system,s pace groupP1with a=0.9634(2),b=0.9678(2),c=0.9713(2)nm,α=111.18(3),β=114.61(3),γ=99.05(3)°,V=0.7154(2)nm 3 ,Z =1,F(000)=333,D c =1.531g·cm -3 ,μ(Mo Kα)=0.819mm -1 .The structure was refined to R=0.0595and w R=0.1769for observed 2708reflection s with I≥2σ(I).In both structures the Co ?ions are six-coordinated to form distorted octahedron.Two Co ?complexes Co (β-diketonate) 2(py) 2Co (bzac)2 (py) 2(1)andCo (tta) 2 (py) 2(2)(bzacH =benzoylacetone,ttaH =2-thenoyltr ifluoroacetone,py =pyridine)were synthesized and characterized by X-ray diffraction.Complex1crystallizes in monoclinic system,space group P2 1 /n with a=0.7409(2),b=1.7430(4),c=1.0527(2)nm,β=102.23(3)°,V=1.3285(5)nm 3 ,Z =2,F(000)=562,D c =1.349g·cm -3 ,μ(Mo Kα)=0.684mm -1 .The structure was refined to R=0.0307and w R=0.0827for observed 2437reflectio ns with I≥2σ(I).Complex2crystallizes in triclinic system,s pace groupP1with a=0.9634(2),b=0.9678(2),c=0.9713(2)nm,α=111.18(3),β=114.61(3),γ=99.05(3)°,V=0.7154(2)nm 3 ,Z =1,F(000)=333,D c =1.531g·cm -3 ,μ(Mo Kα)=0.819mm -1 .The structure was refined to R=0.0595and w R=0.1769for observed 2708reflection s with I≥2σ(I).In both structures the Co ?ions are six-coordinated to form distorted octahedron.

关 键 词：Co(Ⅱ)配合物 苯甲酰丙酮 2-噻吩甲酰三氟丙酮 晶体结构 

分 类 号：O632.12[理学—高分子化学] O643.361[理学—化学]