二茂铁衍生物的合成和表征  

Synthesis and Characterization of Ferrocene Derivatives

作　　者：陈勇[1] 杨光[1] 张新兵[1] 刘惠英[2] 

机构地区：[1]江苏石油化工学院化学工程系,江苏常州213016 [2]武汉大学化学系,湖北武汉430072

出　　处：《江苏石油化工学院学报》2002年第2期14-16,共3页Journal of Jiangsu Institute of Petrochemical Technology

基　　金：江苏石油化工学院科研基金资助

摘　　要：由二茂铁和芳胺作为原料通过芳基化作用合成了 3个新二茂铁衍生物。通过元素分析、IR、1 HNMR和MS确证了化合物结构。In the investigation,three new ferrocene derivatives were synthesized by arylation,using ferrocene and arylamines as the starting materials.The structures of these new derivatives were confirmed by elementary analysis,IR, 1HNMR and MS.The other properties and uses of these compounds are yet to be studied.The yields of three products were 17 3%,10 2% and 20 3%,respectively.The tests found that the key step is the preparation of diazotization of arylamine.The result showed that the appropriate reaction conditions should be:sulfuric acid as reaction medium;at room temperature.

关 键 词：二茂铁衍生物 合成 表征 二茂铁 芳胺 芳基化 

分 类 号：O627.81[理学—有机化学]