11-溴代十一酸的合成研究  

Synthesis of 11-Bromoundecanoic Acid

作　　者：崔建兰[1] 

机构地区：[1]华北工学院,山西太原030051

出　　处：《辽宁化工》2002年第4期141-142,154,共3页Liaoning Chemical Industry

摘　　要：11-溴代十一酸是尼龙 - 11单体的中间体 ,以 10 -十一烯酸和溴化氢为原料合成 11-溴代十一酸 ,通过实验得出了溴代反应的最佳工艺条件为 :引发剂用量 2 % ,溴代温度 0～ 15℃ ,反应时间 1h ,溶剂为甲苯 ,10 -十一烯酸与甲苯的最佳配比 2 0 % ,上述条件下 ,溴代反应的收率达 92bromoundecanoic acid was intermediate product of nylon-11,It was synthesized with 10-undecanoic acid and hydrobromic acid as raw materials .The experimental results showed that optimal reaction conditions were that initiating agent to reactants was 2%, the reaction temperature was 0～15℃, the reaction time was 1h, the solvent was toluene, the mass of ratio of 10-undecanoic acid to toluene was 20%. under these conditions, the brominating reaction yield was 92 %.

关 键 词：11-溴代十一酸 合成 10-十一烯酸 尼龙-11 中间体 

分 类 号：TQ225.3[化学工程—有机化工] TQ323.6