具有内孔道的层状超分子化合物[(CuI)_2(o-phen)_2]的水热合成与晶体结构  

Hydrothermal Synthesis and Crystal Structure of a Layered Inner-tunnel Compound [(CuI)_2(o-phen)_2]

作　　者：王树涛[1] 王恩波[1] 李阳光[1] 王力[1] 胡长文[1] 胡宁海[2] 贾恒庆[2] 

机构地区：[1]东北师范大学化学学院,长春130024 [2]中国科学院长春应用化学研究所,长春130022

出　　处：《高等学校化学学报》2002年第7期1241-1242,共2页Chemical Journal of Chinese Universities

基　　金：国家自然科学基金 (批准号 :2 0 17810 10 )

摘　　要：A layered inner tunnel supramolecular compound 1, [(CuI) 2( o phen) 2], was hydrothermally synthesized and structurally characterized by X ray crystal diffraction. It crystallizes in triclinic system, space group P 1 with a =0.775 9(2) nm, b =0.907 0(2) nm, c =0.918 94(10) nm, α =96 306(14)°, β = 104.567(16)°, γ =109.421(19)°, V =0.576 8(2) nm 3, Z=1, R=0.034 8, wR =0.092 0.A layered inner tunnel supramolecular compound 1, [(CuI) 2( o phen) 2], was hydrothermally synthesized and structurally characterized by X ray crystal diffraction. It crystallizes in triclinic system, space group P 1 with a =0.775 9(2) nm, b =0.907 0(2) nm, c =0.918 94(10) nm, α =96 306(14)°, β = 104.567(16)°, γ =109.421(19)°, V =0.576 8(2) nm 3, Z=1, R=0.034 8, wR =0.092 0.

关 键 词：层状超分子化合物 [(CuI)2(o-phen)2] 氢键水热合成 晶体结构 双核铜卤化合物 

分 类 号：O641.3[理学—物理化学] O614.121[理学—化学]