Sm金属富勒烯的高效提取和电化学性质研究  

Highly Effective Extraction and Electrochemical Properties of Sm-metallofullerene

作　　者：孙宝云[1] 李美仙[1] 顾镇南[1] 

机构地区：[1]北京大学化学与分子工程学院,北京100871

出　　处：《高等学校化学学报》2002年第7期1389-1391,共3页Chemical Journal of Chinese Universities

基　　金：国家重点自然科学基金 (批准号 :2 0 15 10 0 2 )资助

摘　　要：Sm@C 82 (Ⅲ) was effectively extracted by the high temperature DMF extraction and separated in one step HPLC, making the further studies of its properties possible. The successful purification of Sm metallofullerene with such a low yield indicates that the high temperature DMF extraction is much effective. The cyclic and differential pulse voltammgrams of the pure Sm@C 82 (Ⅲ) were first measured, indicating that it has a good electron accepted ability. Up to 6 electrons can be added to them. The analysis of the potentials, the potential differential and the number of electron transferred show that Sm prefers to take +2 charge state in the carbon cage. The study of electronic structure would help us to produce, extract more metallofullerenes and synthesize useful materials.Sm@C 82 (Ⅲ) was effectively extracted by the high temperature DMF extraction and separated in one step HPLC, making the further studies of its properties possible. The successful purification of Sm metallofullerene with such a low yield indicates that the high temperature DMF extraction is much effective. The cyclic and differential pulse voltammgrams of the pure Sm@C 82 (Ⅲ) were first measured, indicating that it has a good electron accepted ability. Up to 6 electrons can be added to them. The analysis of the potentials, the potential differential and the number of electron transferred show that Sm prefers to take +2 charge state in the carbon cage. The study of electronic structure would help us to produce, extract more metallofullerenes and synthesize useful materials.

关 键 词：SM 金属富勒烯 提取 电化学性质 钐 高效液相色谱 

分 类 号：O635[理学—高分子化学] O646.5[理学—化学]