新型钼磷酸有机衍生物(催化剂)的结构、制备和应用  

THE STRUCTURE,PREPARATION AND APPLICATION OF NEW ORGANIC DERIVATIVES OF PHOSPHO-MOLYBDIC ACIDS(CATALYST)

作　　者：秦玉楠 

机构地区：[1]成都慧龙化工厂专家组,成都610306

出　　处：《中国钼业》2002年第3期7-9,共3页China Molybdenum Industry

摘　　要：摘要 [(EDTB)Me](CH3 COO) 2 和钼磷酸 (H3 PMo12 O4 0 )在无水乙醇中反应得到新型钼磷酸有机衍生物 [(EDTB)Me](HPM12 O4 0 ) ,Me为Cu、Co ,EDTB为N ,N ,N′ ,N′ -四 [(2 -苯并咪唑 )甲基 ]- 1,2 -乙二胺。测定了它的PMR、IR、紫外 -可见光谱。H3PMo 12O 40),Me=Cu?Co,were prepared by the reaction of (CH 3COO) 2 with H 3PMo 12O 40 in absolute ethanol,in which EDTB is N,N,N′,N′-tetrakis[(2-benzimidazolyl)methyl]-1,2-ethylenediamine.The structure of the title compounds was characterized by PMR IR,UV-Vis,elemental analysis and crystal structure,and the catalytic activities of esterification of chloroacetic acid and pyrolytic elimination of cyclohexyl acetate were also determined,etc.

关 键 词：钼磷酸有机衍生物 弱“金属-氮”键配合物 四[(苯咪唑)甲基]乙二胺(EDTB) 酯化反应 热消除反应 催化活性 

分 类 号：O643.3[理学—物理化学]