混合价三核锰配合物Mn_3O(O_2CCCl_3)_6(py)_2(H_2O)的合成、晶体结构及磁性(英文)  

Synthesis,Crystal Structure and Magnetic Property of a New Mixed-V alence Trinuclear Oxo-Centered Manganese Complex Mn_3O(O_2CCCl_3)_6(py)_2(H_2O)

作　　者：黄辉[1] 王天维[1] 李一志[1] 游效曾[1] 

机构地区：[1]南京大学配位化学研究所配位化学国家重点实验室

出　　处：《无机化学学报》2002年第8期797-801,共5页Chinese Journal of Inorganic Chemistry

基　　金：国家自然科学基金资助项目(No.90101028和29929001)

摘　　要：A new mixed-valence trinuclear oxo-centered manganese complex Mn3O(O2CCC l3)6(py)2(H2O) was prepared by the reaction of NnBu4MnO4 with Mn(OAc)2·4H2O, t richloroacetic acid and pyridine in absolute EtOH. The crystal structure was det ermined. The complex crystallizes in monoclinic, space group P21/c, unit cell pa rameters, a=14.951(1), b=20.791(2), c=17.882(1),á=?=90a=102.67(1)A new mixed-valence trinuclear oxo-centered manganese complex Mn3O(O2CCC l3)6(py)2(H2O) was prepared by the reaction of NnBu4MnO4 with Mn(OAc)2·4H2O, t richloroacetic acid and pyridine in absolute EtOH. The crystal structure was det ermined. The complex crystallizes in monoclinic, space group P21/c, unit cell pa rameters, a=14.951(1), b=20.791(2), c=17.882(1),á=?=90a=102.67(1)

关 键 词：混合介三核锰配合物 Mn3O(O2CCCL3)6(ph)2(H2O) 合成 晶体结构 X射线衍射 磁性 

分 类 号：O614.711[理学—无机化学] O766.3[理学—化学]