碳钢在管流体系中的流动腐蚀动力学模型  

FLOW-INDUCED CORROSION KINETICS MODEL OF CARBON STEEL IN FLOW LOOP SYSTEM

作　　者：雍兴跃[1] 林玉珍[1] 刘景军[1] 贺志鹏[1] 

机构地区：[1]北京化工大学材料科学与工程学院

出　　处：《化工学报》2002年第7期680-684,共5页CIESC Journal

基　　金：国家自然科学基金资助项目 (No .5 0 10 10 0 2 )~~

摘　　要：针对管流体系 ,根据动量、能量和质量守恒原理 ,应用壁函数、k -ε湍流运动模型确立了管流体系中的计算流体力学模型和质量传递模型 ;结合必要的实验分析碳钢流动腐蚀过程中的主要控制因素及其影响程度 ,建立了碳钢在流动的 3.5 %NaCl溶液中的流动腐蚀动力学模型 .同时 ,采用数值计算方法计算了流动腐蚀速度 ,并与实验结果进行了验证 .Wall function, k-ε turbulence model are used in the present study.The numerical hydrodynamics models and mass transfer models in flow loop system are defined in accordance with the basic theory of hydrodynamics and conservation of mass,momentum or energy.Flow-induced corrosion kinetics model of carbon steel in flowing 3.5% NaCl solution is set up on the basis of determining main controlling factors and analyzing their degree of influence in flow-induced corrosion by some electrochemical experiments. The numerical method used in this study is based on the control volume approach for discretization of partial differential equations that express the characteristics of fluid flow and mass transfer.The power law scheme is also used in discretization of convection-diffusion equations.In this manner,the resulting discretization equations express the conservation principle for mass,momentum and energy over the finite control volume,just as the differential equations express the same principle for the infinitesimal volume.In this way,the formulation is straightforward.The user program is compiled.In accordance with flow-induced corrosion kinetics models,flow-induced corrosion rates are numerically calculated with SIMPLE algorithm.The flow-induced corrosion rates calculated by numerical method are compared with the ones measured by weight loss.The numerically computed flow-induced corrosion rates are mostly equal to the ones measured by weight loss experiments.If proves that the flow-induced corrosion kinetics models are correct and accurate,and that the user program is reasonable.The models are founded on the basis of some electrochemical experiments and reasonable hypothesis.Corrosion electrochemical factor plays a dominant role in flow-induced corrosion of carbon steel in flowing 3.5% NaCl solution.

关 键 词：碳钢 流动氯化物 管流体系 壁函数 κ-ε湍流模型 流动腐蚀 动力学模型 电化学 流体动力学 质量传递模型 

分 类 号：TG171[金属学及工艺—金属表面处理]