新型有机/无机聚合物网络的合成与二阶非线性光学  

SYNTHESIS AND SECOND-ORDER NONLINEARITY OF NOVEL ORGANIC/INORGANIC NETWORK BY SOL-GEL PROCESS

作　　者：王坚[1] 张灵志[1] 陈用烈[1] 梁兆熙[1] 蔡志岗[2] 

机构地区：[1]中山大学化学化工学院高分子研究所,广州510275 [2]中山大学光电材料与技术国家重点实验室,广州510275

出　　处：《感光科学与光化学》2002年第4期276-282,共7页Photographic Science and Photochemistry

基　　金：国家自然科学基金 ( 1 96 0 4 0 1 5 );广东省自然科学基金 ( 980 34 6;0 0 1 2 4 9)

摘　　要：合成了含双官能团的生色团 4′ (N ,N 二羟乙基 )氨基 4 硝基偶氮苯(DR1 9) ,采用溶胶 凝胶方法 ,通过“两端”交联设计合成了光学性能良好的二阶非线性新型有机 /无机复合聚合物网络 .经过极化交联后 ,其在室温和较高温度下均具有良好的二次谐波产生 (SHG)稳定性 ,表明该交联聚合体系能形成致密的硅 氧网络 。Chromophore with two active OH groups 4'-(N,N-dihydroxyethyl)amino-4-nitroazobenzene(DR19) was synthesized and a novel organic/inorganic polymer network with fine second-order nonlinearities was designed and prepared by double-end crosslinking of DR19 through sol-gel process.It was observed that this polymer film had good SHG thermal stability under room and elevated temperatures.The results show that this crosslinking system formed a dense silicon-oxygen network structure,thus could effectively inhibit the orientation relaxation of the chromophore molecules and hence improve the thermal stability of second-order nonlinearity of the material.

关 键 词：二阶非线性光学 溶胶-凝胶 有机/无机聚合物网络 极化交联 偶氮苯生色团 

分 类 号：O648[理学—物理化学]