化学机械法制浆废液中污染物质的白腐菌降解 第3部分 白腐菌生化降解前后废液的气相色谱/质谱分析  

Biodegradation of Pollutants in CTMP Effluent by White-Rot Fungi Phanerochaete Chrysosporium

作　　者：高扬[1] 闫冰[1] 张曾[1] 陈港[1] 谢国辉[1] 

机构地区：[1]华南理工大学制浆造纸工程国家重点实验室,广州510640

出　　处：《中国造纸学报》2002年第1期44-47,共4页Transactions of China Pulp and Paper

基　　金：广东省自然科学基金;教育部留学回国人员科研启动基金;制浆造纸工程国家重点实验室基金的资助

摘　　要：在采用白腐菌处理化学机械法制浆废液探索研究的基础上 ,利用气相色谱 /质谱联用检测技术 ,分析了生化处理前后废液中有机污染物的变化。研究结果表明 ,CTMP制浆废液中的毒性有机污染物主要为含有不同取代基的芳香族酚类、醇类、醛类、醚类、酯类和有机酸类等。预处理段废液和磨浆段废液相比 ,主要污染成分的相对含量存在着差异。经过白腐菌生化处理之后 ,废液中检测出来的污染物种类和含量均发生了明显变化 ,多种芳香族化合物的结构及其联接键发生断裂破坏 ,废液有机污染物的毒性显著降低。Based on previous trudies of CTMP effluent bio-treatment by white rot-fungi phanerochaete chrysosporium, pollutants in the effluents were determined by GC/MC analysis. It showed that pollutants are mainly aromatic organisms with different substitutes, such as aldehydes, aethers, esters, as well as organic acids and so on. Some differences of contaminant contents between the effluent of pretreatment stage of CTMP and the effluent of refining stage were discovered. Changes of contaminant species and contents took place after bio-treatment. Aromatic structures and linkages were found broken to some extent, which lead to accordingly decreased toxicity.

关 键 词：污染物质 化学机械法制浆废液 白腐菌降解 气相色谱/质谱分析 造纸 生化处理 

分 类 号：X793[环境科学与工程—环境工程]