六氢苯二甲酸酐的制备
PREPARATION OF HEXAHYDROPHTHALIC ANHYDRIDE</em>
<p class='article-op'>
<span id="bdshare" class="bdshare_t bds_tools get-codes-bdshare baidufx"><span><span
class="bds_more" style="display: block; width: 62px; height: 29px; background: url(/images/share.gif) no-repeat!important; padding: 0;"></span></span></span>
</p>
<p class="article-source">
<a href ='/article/read.aspx?id=6591987' class='btnTitle btnIsView' target='_blank'><img alt='在线阅读' src='/images/btn-read.png'/></a><a class='btnTitle btnIsView' href="javascript:showdown('X+3YGK+RMDf0LmLr55iFKrjkFwb459FmAPlllV5fxkM=')"><img alt="下载全文" src="/images/btn-down.png" /></a>
<input id="hiddowninfo" type="hidden" value="X+3YGK+RMDf0LmLr55iFKrjkFwb459FmAPlllV5fxkM="/>
</p>
<div class="collect" style="display: none">
<h5>我的收藏</h5>
<div class="cnt">
<p>
名 称：<input type="text" name="collTitle" id="collSumTitle" />
</p>
<p>
注 释：<input type="text" name="collRemark" id="collSumRemark" />
</p>
<p style="text-align: center;">
<a href="javascript:void(0)" onclick="g_collectSumOk();">
<img width="65" height="17" src="/images_new/collect_ok.png" alt="完成" /></a>
<a href="javascript:void(0)" onclick="g_collectSumCancel();">
<img width="65" height="17" src="/images_new/collect_no.png" alt="取消" /></a>
</p>
</div>
</div>
</div>
<form name="wxTransfer" method="post">
<input type="hidden" name="lid" value="" />
<input type="hidden" name="sip" value="" />
<input type="hidden" name="date" value="" />
<input type="hidden" name="co" value="" />
<input type="hidden" name="Title_C" value="" />
<input type="hidden" name="Writers" value="" />
<input type="hidden" name="Name_C" value="" />
<input type="hidden" name="Num" value="" />
<input type="hidden" name="Years" value="" />
<input type="hidden" name="Volumn" value="" />
<input type="hidden" name="GCH" value="" />
<input type="hidden" name="Vol" value="" />
<input type="hidden" name="BookID" value="" />
<input type="hidden" name="SubjectNum" value="" />
<input type="hidden" name="SpecialNum" value="" />
<input type="hidden" name="mirrorName" value="" />
<input type="hidden" name="UserID" value="" />
<input type="hidden" name="UserName" value="" />
<input type="hidden" name="sourceID" value="" />
</form>
<script type="text/javascript" src="/scripts/transfer.min.js"></script>
<div class="article-detail">
<p class='author'><strong>作 者：</strong><a href='/writer/article.aspx?id=100000015786222' target='_blank' ><b class='type_ico_id'></b></a><a href='/zk/search.aspx?key=A%3d%5b%e6%9d%a8%e7%91%9e%e5%a8%9c%5d' title='杨瑞娜[1]'>杨瑞娜[1]</a> <a href='/writer/article.aspx?id=100000015488126' target='_blank' ><b class='type_ico_id'></b></a><a href='/zk/search.aspx?key=A%3d%5b%e6%9c%b1%e9%9b%81%5d' title='朱雁[1]'>朱雁[1]</a> <a href='/writer/article.aspx?id=100000015759384' target='_blank' ><b class='type_ico_id'></b></a><a href='/zk/search.aspx?key=A%3d%5b%e8%b0%a2%e9%9d%92%5d' title='谢青[2]'>谢青[2]</a> <a href='/writer/article.aspx?id=100000006076944' target='_blank' ><b class='type_ico_id'></b></a><a href='/zk/search.aspx?key=A%3d%5b%e9%82%9d%e7%88%b1%e7%87%95%5d' title='邝爱燕[1]'>邝爱燕[1]</a> <em> </em></p><p class='organ'><strong>机构地区：</strong><a href='/organ/article.aspx?id=661270&subid=&showname=&searchtype=' target='_blank'><b class='type_ico_id'></b></a><a href='/zk/search.aspx?key=S%3d%e6%b2%b3%e5%8d%97%e7%9c%81%e5%8c%96%e5%ad%a6%e7%a0%94%e7%a9%b6%e6%89%80' title='[1]河南省化学研究所,河南郑州450002'>[1]河南省化学研究所,河南郑州450002</a> <a href='/organ/article.aspx?id=59665&subid=&showname=&searchtype=' target='_blank'><b class='type_ico_id'></b></a><a href='/zk/search.aspx?key=S%3d%e5%9b%bd%e5%ae%b6%e6%9e%97%e4%b8%9a%e5%b1%80%e6%b3%a1%e6%a1%90%e7%a0%94%e7%a9%b6%e5%bc%80%e5%8f%91%e4%b8%ad%e5%bf%83' title='[2]国家林业局泡桐研究开发中心,河南郑州450003'>[2]国家林业局泡桐研究开发中心,河南郑州450003</a> <em> </em></p><p class='from'><strong>出 处：</strong><a href='/journal/summary.aspx?gch=98094X' target='_blank'><b class='type_ico_id'></b></a><a href='/zk/search.aspx?key=J%3d%5b%e7%83%ad%e5%9b%ba%e6%80%a7%e6%a0%91%e8%84%82%5d' title='热固性树脂'>《热固性树脂》</a>2002年第4期5-7,共3页<em>Thermosetting Resin</em></p><p class='fund'><strong>基 金：</strong>河南省杰出青年基金资助项目(9910);河南省科技攻关资助项目(001090106)</p><p class='abstrack'><strong>摘 要：</strong>进行了四氢苯酐催化加氢制备六氢苯酐的合成工艺研究,分别对温度、压力、催化剂等因素对加氢反应的影响进行了研究,确定了最佳反应条件。与传统的镍系催化剂相比较,采用溶剂法工艺、使用国内首创的钯系复合型催化剂合成六氢苯二甲酸,具有催化效率高,反应时间短,反应温度低,六氢苯二甲酸酐选择性100%,所得产品质量稳定等优点,其产品质量达到国外类似产品的水平。<em><Abstrcat>The preparation of the title compound,hexahydrophthalic anhydride,via hydrogenation of tetrahydrophthalic anhydride had been presented in this article.The hydrogenation affecting factors,such as temperature,pressure and catalyst,had been discussed.The optimum reaction conditions were determined.Compared with traditional nickel catalyst,using palladium complex catalyst,displayed many advantages,for example,the catalytic coefficientof performance (CCOP)was higher,reaction time was shorter,reaction temperature was lower,and selectivity for hexahydrophthalic anhydride was 100%.The quality of product prepared in laboratory reached the level of same product abroad.</em></p><p class='subject'><strong>关 键 词：</strong><a href='/zk/search.aspx?key=K%3d%5b%e5%85%ad%e6%b0%a2%e8%8b%af%e4%ba%8c%e7%94%b2%e9%85%b8%e9%85%90%5d' title='六氢苯二甲酸酐'>六氢苯二甲酸酐</a> <a href='/zk/search.aspx?key=K%3d%5b%e5%88%b6%e5%a4%87%5d' title='制备'>制备</a> <a href='/zk/search.aspx?key=K%3d%5b%e5%85%ad%e6%b0%a2%e8%8b%af%e9%85%90%5d' title='六氢苯酐'>六氢苯酐</a> <a href='/subject/article.aspx?id=2428435' target='_blank'><b class='type_ico_id'></b></a><a href='/zk/search.aspx?key=K%3d%5b%e5%9b%9b%e6%b0%a2%e8%8b%af%e9%85%90%5d' title='四氢苯酐'>四氢苯酐</a> <a href='/subject/article.aspx?id=9233540' target='_blank'><b class='type_ico_id'></b></a><a href='/zk/search.aspx?key=K%3d%5b%e5%82%ac%e5%8c%96%e6%b0%a2%e5%8c%96%5d' title='催化氢化'>催化氢化</a> </p><p class='class'><strong>分 类 号：</strong><a href='/zk/search.aspx?key=C%3dTQ245.23' title='TQ245.23'>TQ245.23</a>[<a href = '/domain/article.aspx?id=126' >化学工程—有机化工</a>] </p>
</div>
<div id="content_wzxg" name="wzxg" class="article-graph">
<object width="695" height="250" classid="clsid:D27CDB6E-AE6D-11cf-96B8-444553540000"
id="FlashID">
<param value="../flash/relation.swf" name="movie">
<param value="high" name="quality">
<param value="opaque" name="wmode">
<param value="6.0.65.0" name="swfversion">
<param value="dataUrl=/ajax/articlerelativegraph.ashx?id=6591987" name="flashVars">
<embed width="695" height="250"
src="../flash/relation.swf" type="application/x-shockwave-flash" quality="high"
wmode="opaque" flashvars="dataUrl=/ajax/articlerelativegraph.ashx?id=6591987">
</embed>
</object>
</div>
<div class="article-relate-list">
<div class="relate-list">
<p id="ckwx_br"> </p>
<h2 name="ckwx" id="ckwx">参考文献：</h2>
<div id="listckwx">
<p class='submit'>
<img src='/images/loading.gif' width='16' height='16' />
正在载入数据...
</p>
</div>
</div>
<div class="relate-list">
<p id="2jckwx_br"> </p>
<h2 name="2jckwx" id="2jckwx">二级参考文献：</h2>
<div id="list2jckwx">
<p class='submit'>
<img src='/images/loading.gif' width='16' height='16' />
正在载入数据...
</p>
</div>
</div>
<div class="relate-list">
<p id="ohwx_br"> </p>
<h2 name="ohwx" id="ohwx">耦合文献：</h2>
<div id="listohwx">
<p class='submit'>
<img src='/images/loading.gif' width='16' height='16' />
正在载入数据...
</p>
</div>
</div>
<div class="relate-list">
<p id="yzwx_br"> </p>
<h2 name="yzwx" id="yzwx">引证文献：</h2>
<div id="listyzwx">
<p class='submit'>
<img src='/images/loading.gif' width='16' height='16' />
正在载入数据...
</p>
</div>
</div>
<div class="relate-list">
<p id="2jyzwx_br"> </p>
<h2 name="2jyzwx" id="2jyzwx">二级引证文献：</h2>
<div id="list2jyzwx">
<p class='submit'>
<img src='/images/loading.gif' width='16' height='16' />
正在载入数据...
</p>
</div>
</div>
<div class="relate-list">
<p id="tbywx_br"> </p>
<h2 name="tbywx" id="tbywx">同被引文献：</h2>
<div id="listtbywx">
<p class='submit'>
<img src='/images/loading.gif' width='16' height='16' />
正在载入数据...
</p>
</div>
</div>
<div class="relate-list">
<p id="xgqklw_br"> </p>
<h2 name="xgqklw" id="xgqklw">相关期刊文献：</h2>
<div id="listxgqklw">
<p class='submit'>
<img src='/images/loading.gif' width='16' height='16' />
正在载入数据...
</p>
</div>
</div>
</div>
</div>
<div class="article-about">
<div class="about-box">
<h5 class="name">相关的主题<tt><a class="hide" href="#"></a></tt></h5>
<div class="about-list">
</div>
</div>
<div class="about-box">
<h5 class="name">相关的作者对象<tt><a class="" href="#"></a></tt></h5>
<div class="about-list" style="display: none;">
</div>
</div>
<div class="about-box">
<h5 class="name">相关的机构对象<tt><a class="" href="#"></a></tt></h5>
<div class="about-list" style="display: none;">
</div>
</div>
</div>
</div>
</div>
<script type="text/javascript" src="/scripts/articlerelation.min.js"></script>
<script type="text/javascript" src="/scripts/articlerightrelation.min.js"></script>
<script type="text/javascript" src="/scripts/articledown.min.js"></script>
<div class="layer-box download" id="downloadlayer" style="display: none">
<div class="close">
<a onclick="closedown()" href="javascript:void(0)">
<img src="/images/layer-close.png" width="21" height="21" alt="" />
</a>
</div>
<h5 class="layer-title">下载全文</h5>
<div id="downloadinfo"></div>
</div>
<div class="layer-box download" id="downloadlayer2" style="display:none;min-height:100px;width:500px;">
<p>
<img src="/images/loading2.gif" width="64" height="64">
<span style="font-size:20px;vertical-align:middle;padding-bottom:50px;">正在链接到云南高校图书馆文献保障联盟下载...</span>
</p>
</div>
<script id="bdshare_js" data="type=tools&uid=0" type="text/javascript"></script>
<script type="text/javascript">
$(function () {
var rd = GetQueryString("rd");
if (rd == "readdown") {
var val = $("#hiddowninfo").val();
showdown(val);
}
$("#bdshare_js").attr("src","http://bdimg.share.baidu.com/static/js/bds_s_v2.js?cdnversion="+Math.ceil(new Date() / 3600000));
})
</script>
<div class="layer-bg" style="display: none;"></div>
<script type="text/javascript" src="/scripts/login.min.js"></script>
<div class="layer-box login" id="divLoginBox" style="display: none;">
<div class="close"><a href="javascript:void(0);" id="btnLoginClose">
<img src="/images/layer-close.png" width="21" height="21" alt="" title="关闭" /></a></div>
<h5 class="layer-title">用户登录</h5>
<div class="layer-cnt">
<div class="search-list adv-object">
<div class="login-alert" id="divLoginError"></div>
<div class="sinput">
<div class="input"><span class="user-ico"></span>
<input type="text" id="txtLUsername" name="txtLUsername" maxlength="20"></div>
</div>
<div class="sinput">
<div class="input"><span class="psw-ico"></span>
<input type="password" id="txtLPassword" name="txtLPassword" maxlength="20"></div>
</div>
<div class="submit">
<input type="button" value="登录" onclick="return normalLogin(loginAfter)" name="" class="btn-s"><input value="IP登录" onclick=" return ipLogin(loginAfter)" type="button" class="btn-c">
</div>
</div>
</div>
</div>
<div id="footer">
<p>
云南高校图书馆联盟文献共享服务平台
版权所有©
<script type="text/javascript">
document.write(new Date().getFullYear());
</script>
</p>
<p>
您的IP：216.73.216.3
</p>
</div>
<input id="hifBaseLog" type="hidden" value="OTgwOTRYOzY1OTE5ODc7VFEyNDUuMjM7MDs7L2FydGljbGUvZGV0YWlsLmFzcHg="/>
<script type="text/javascript">
$(document).ready(function () {
$("#loginLoading").load("/user/loginheader.aspx?" + Math.random());
});
</script>
<script>
var _hmt = _hmt || [];
(function () {
var hm = document.createElement("script");
hm.src = "//hm.baidu.com/hm.js?36a05ff8f5e8a5be3ff03e1d75c8a9d1";
var s = document.getElementsByTagName("script")[0];
s.parentNode.insertBefore(hm, s);
})();
</script>
<script>
(function (i, s, o, g, r, a, m) {
i['GoogleAnalyticsObject'] = r; i[r] = i[r] || function () {
(i[r].q = i[r].q || []).push(arguments)
}, i[r].l = 1 * new Date(); a = s.createElement(o),
m = s.getElementsByTagName(o)[0]; a.async = 1; a.src = g; m.parentNode.insertBefore(a, m)
})(window, document, 'script', '//www.google-analytics.com/analytics.js', 'ga');
ga('create', 'UA-2219013-37', 'auto');
ga('send', 'pageview');
</script>
</body>
</html>
