聚三烯丙基异氰尿酸酯的合成研究
RESEARCH ON SYNTHESIS OF POLY (TRIALLYL ISOCYANURATE)</em>
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<p class='author'><strong>作 者：</strong><a href='/writer/article.aspx?id=100000013525795' target='_blank' ><b class='type_ico_id'></b></a><a href='/zk/search.aspx?key=A%3d%5b%e8%b5%b5%e5%b0%8f%e5%b9%b3%5d' title='赵小平[1]'>赵小平[1]</a> <a href='/writer/article.aspx?id=100000005758144' target='_blank' ><b class='type_ico_id'></b></a><a href='/zk/search.aspx?key=A%3d%5b%e6%9d%8e%e7%bb%8d%e6%96%87%5d' title='李绍文[1]'>李绍文[1]</a> <a href='/writer/article.aspx?id=100000003085706' target='_blank' ><b class='type_ico_id'></b></a><a href='/zk/search.aspx?key=A%3d%5b%e6%9d%a8%e5%86%9b%5d' title='杨军[1]'>杨军[1]</a> <a href='/writer/article.aspx?id=100000006237812' target='_blank' ><b class='type_ico_id'></b></a><a href='/zk/search.aspx?key=A%3d%5b%e4%b8%81%e5%90%91%e4%b8%9c%5d' title='丁向东[1]'>丁向东[1]</a> <a href='/writer/article.aspx?id=100000007359048' target='_blank' ><b class='type_ico_id'></b></a><a href='/zk/search.aspx?key=A%3d%5b%e5%b0%a4%e8%a3%95%e5%a6%82%5d' title='尤裕如[1]'>尤裕如[1]</a> <em> </em></p><p class='organ'><strong>机构地区：</strong><a href='/organ/article.aspx?id=215&subid=&showname=&searchtype=' target='_blank'><b class='type_ico_id'></b></a><a href='/zk/search.aspx?key=S%3d%e5%ae%89%e5%be%bd%e7%9c%81%e5%8c%96%e5%b7%a5%e7%a0%94%e7%a9%b6%e9%99%a2' title='[1]安徽省化工研究院,安徽合肥230041'>[1]安徽省化工研究院,安徽合肥230041</a> <em> </em></p><p class='from'><strong>出 处：</strong><a href='/journal/summary.aspx?gch=98094X' target='_blank'><b class='type_ico_id'></b></a><a href='/zk/search.aspx?key=J%3d%5b%e7%83%ad%e5%9b%ba%e6%80%a7%e6%a0%91%e8%84%82%5d' title='热固性树脂'>《热固性树脂》</a>2002年第4期8-9,17,共3页<em>Thermosetting Resin</em></p><p class='fund'><strong>基 金：</strong>.NULL.</p><p class='abstrack'><strong>摘 要：</strong>采用卤代烃为溶剂和调聚剂,在引发剂存在下,使三烯丙基异氰尿酸酯(TAIC)预聚,制备了一种新型的热固性树脂聚三烯丙基异氰尿酸酯(P-TAIC),其溴值为100g～140g/g,软化点大于200℃。讨论了引发剂、溶剂、单体浓度对预聚反应的影响,测定了预聚反应的平均转化率约为40%,考察了未聚合单体的循环使用情况。<em><Abstrcat>Halogenated hydrocarbons being used as solvents and telogens,in the presence of an initiator,a new type of thermosetting resin,poly(triallyl isocyanurate)(P-TAIC) was manufactured by pre-polymerization or telomerization of triallyl isocyanurate(TAIC).The bromine value of P-TAIC was 100～140 g/100 g and softening point was over 200℃.Effect of the initiators,the solvents and the concentration of the monomer on the pre-polymerization were discussed.It was measured that average conversion ratio of pre-polymerization was approximately 40%.Recycle of the unreacted monomer was also tested.</em></p><p class='subject'><strong>关 键 词：</strong><a href='/zk/search.aspx?key=K%3d%5b%e8%81%9a%e4%b8%89%e7%83%af%e4%b8%99%e5%9f%ba%e5%bc%82%e6%b0%b0%e5%b0%bf%e9%85%b8%e9%85%af%5d' title='聚三烯丙基异氰尿酸酯'>聚三烯丙基异氰尿酸酯</a> <a href='/zk/search.aspx?key=K%3d%5b%e5%90%88%e6%88%90%5d' title='合成'>合成</a> <a href='/zk/search.aspx?key=K%3d%5b%e7%a0%94%e7%a9%b6%5d' title='研究'>研究</a> <a href='/zk/search.aspx?key=K%3d%5b%e4%b8%89%e7%83%af%e4%b8%99%e5%9f%ba%e5%bc%82%e6%b0%b0%e5%b0%bf%e9%85%b8%e9%85%af%5d' title='三烯丙基异氰尿酸酯'>三烯丙基异氰尿酸酯</a> <a href='/subject/article.aspx?id=1223258' target='_blank'><b class='type_ico_id'></b></a><a href='/zk/search.aspx?key=K%3d%5b%e9%a2%84%e8%81%9a%e5%90%88%5d' title='预聚合'>预聚合</a> <a href='/zk/search.aspx?key=K%3d%5b%e5%b9%b3%e5%9d%87%e8%bd%ac%e5%8c%96%e7%8e%87%5d' title='平均转化率'>平均转化率</a> </p><p class='class'><strong>分 类 号：</strong><a href='/zk/search.aspx?key=C%3dTQ323' title='TQ323'>TQ323</a>[<a href = '/domain/article.aspx?id=604' >化学工程—合成树脂塑料工业</a>] </p>
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