二维傅里叶变换红外(2D FTIR)相关光谱技术研究聚羟基丁酸酯(PHB)的熔融与结晶  

Studies on Pre-melting and Crystallization Process of Biosynthesized Poly(3-hydroxybutyrate) Using Two-dimensional Fourier-transform Infrared Spectroscopy

作　　者：田格[1] 吴琼[1] 孙素琴[2] 野田勇夫 陈国强[1] 

机构地区：[1]清华大学生物科学与技术系,北京100084 [2]清华大学化学系分析中心,北京100084 [3]The Procter and Gamble Company.8256 Union Centre Boulevard

出　　处：《高等学校化学学报》2002年第8期1627-1631,共5页Chemical Journal of Chinese Universities

基　　金：国家自然科学基金 (批准号 :2 0 0 740 2 0 )资助

摘　　要：应用新型二维傅里叶变换红外 (2 D FTIR)相关光谱研究细菌合成聚羟基丁酸酯 (PHB)在升温时的预熔行为以及降温后的重结晶过程 .在 2 5～ 2 2 0℃的变温过程中测得动态红外光谱 .着重讨论了在热力学干扰导致红外谱图中羰基峰 (1 70 0～ 1 770 cm- 1 )和醚键 (1 2 3 0～ 1 3 1 0 cm- 1 )吸收强度的波动 .结果表明 ,这种影响来自样品中 PHB的结晶态和非晶态之间的相态变化 .二维谱图分析表明 ,在热熔过程中 ,结晶态的消失并不同时引起完全非晶态的出现 ,暗示在分子排列高度有序的晶态和非晶态之间存在某种中间态 ,PHB晶体向非晶态转变时必须经过一个预熔过程 .在红外谱图上这个中间态很可能对应着由二维分析显示出来的位于 1 73 0 cm- 1 的吸收峰 .同时 ,在The pre melting behavior and the crystallization process of bacterially synthesized polyester poly(3 hydroxybutyrate) , abbreviated as the PHB, was investigated by generalized two dimensional Fourier Transform Infrared(2D FTIR) correlation spectroscopy. The temperature dependent dynamic spectra were measured from 25 to 220 ℃. The thermally induced intensity fluctuations of bands for CO ( 1 700-1 770 cm -1 ) and C-O-C groups ( 1 230 - 1 310 cm -1 ) stretching vibrations were discussed. 2D correlation analysis on changes of the crystalline and amorphous conformation indicated that the appearance of fully amorphous component did not accur simultaneously with the disappearance of crystalline component, suggesting that there is an intermediate state between the ordered crystalline and amorphous states in PHB, which may probably responsible for the band near 1 730 cm -1 . Also the intermediate state was observed in the crystallization process of melted amorphous PHB.

关 键 词：二维傅里叶红外光谱 聚羟基丁酸酯 熔融 结晶 预熔过程 生物可降解塑料 

分 类 号：TQ323.4[化学工程—合成树脂塑料工业] O631[理学—高分子化学]