含有酯基二茂铁亚胺环钯化合物催化Suzuki和Heck反应(英文)  

Cyclopalladated ferrocenylimines with ester groups for Heck and Suzuki coupling reactions

作　　者：王炯[1] 穆兵[2] 付志华[1] 汪丽[1] 李铁生[1] 吴养洁[1] 

机构地区：[1]郑州大学化学与分子工程学院、河南省化学生物与有机化学重点实验室、郑州大学先进纳米信息材料实验室,河南郑州450052 [2]郑州师范学院化学系,河南郑州450044

出　　处：《催化学报》2014年第7期1059-1067,共9页

基　　金：supported by the National Natural Science Foundation of China (20973157,J1210060);the Research and Development Founda-tion of Zhengzhou University (2013xjxm020)~~

摘　　要：合成并表征了系列含有酯基二茂铁亚胺环钯化合物.结果表明,该系列环钯催化剂在纯水或有机溶剂中均能高效催化Heck和Suzuki偶联反应.Cyclopalladated ferrocenylimine dimers and cyclopalladated ferrocenylimine monomers were designed and prepared. They were characterized using 1H NMR, 13C NMR, and IR spectroscopies, and MS. The catalytic properties of these compounds in Heck and Suzuki coupling reactions in water or organic solvents were systematically investigated. The results showed that these catalysts could effectively catalyze Heck and Suzuki coupling reactions of aryl or heteroaryl halides in water or organic solvents.

关 键 词：SUZUKI偶联反应 HECK偶联反应 环钯二茂铁亚胺 

分 类 号：O621.251[理学—有机化学]