Progress in the research of radical anion ligands and their complexes  

作　　者：Guoliang Mao Yuanmeng Song Tianjun Hao Ying Li Tao Xu Haiyan Zhang Tao Jiang 

机构地区：[1]Provincial Key Laboratory of Oil & Gas Chemical Technology,College of Chemistry and Chemical Engineering, Northeast Petroleum University

出　　处：《Chinese Science Bulletin》2014年第24期2936-2944,共9页

基　　金：supported by the National Natural Science Foundation of China(20972025,U1362110);PetroChina Innovation Foundation(2013D-5006-0503);Scientific Research Foundation for the Returned Overseas Chinese Scholars,Program for New Century Excellent Talents in University(NCET-07-0142);Heilongjiang Province(41417837-8-08016);Department of Education of Heilongjiang Province(1154H14,1154G53)

摘　　要：Recent progress in the research of radical anion ligands and their complexes with metals were summarized in this review.Radical anions were sorted into several types including iminosemiquinonate and iminoquinonate radical,nitroxide radical,heterocycle radical etc.Structural characteristics and properties of the corresponding complexes were introduced.The complexes exhibited novel properties and possibility for applications in organic magnetic materials and transition metal catalysis.Recent progress in the research of radical anion ligands and their complexes with metals were summarized in this review. Radical anions were sorted into several types including iminosemiquinonate and iminoquinonate radical, nitroxide radical, heterocycle radical etc. Structural characteristics and properties of the corresponding complexes were introduced. The complexes exhibited novel properties and possibility for applications in organic magnetic materials and transition metal catalysis.

关 键 词：阴离子自由基 复合物 配体 过渡金属催化 有机磁性材料 氮氧自由基 配合物 杂环 

分 类 号：O641.4[理学—物理化学]