三(4-硝基苯基)甲醇及其氯化物的合成与表征  

Synthesis and characterization of tris-(4-nitrophenyl)methanol and its chloride derivative

作　　者：蒋清民[1] 徐元清[2] 卞龙骧[2] 徐浩[2] 任艳蓉[2] 丁涛[2] 房晓敏[2] 

机构地区：[1]河南化工职业学院,河南郑州450042 [2]河南大学河南省阻燃与功能材料工程实验室化学化工学院,河南开封475004

出　　处：《化学研究》2014年第4期378-380,共3页Chemical Research

基　　金：河南省科技厅基础前沿项目(13230041033);河南省国际科技合作项目(134300510072);河南省教育厅重点攻关项目(13B530916)

摘　　要：以三苯甲烷为原料,经硝化、氧化和氯化三步反应合成了三(4-硝基苯基)甲烷(TNPM),三(4-硝基苯基)甲醇(TNPMO)和三(4-硝基苯基)氯甲烷(TNPMCl)等一系列三芳基甲烷类化合物.三苯甲烷经混酸硝化制备TNPM;然后经CrO3/冰醋酸氧化生成TNPMO,最后与乙酰氯反应得到TNPMCl.各步产物的结构经核磁共振与红外光谱进行了表征.With triphenylmethane（TPM）as the raw material,a series of triarylmethanes were synthesized,including tis（4-nitrophenyl）methane（TNPM）,tris（4-nitrophenyl）methanol（TNPMO）and tis（4-nitrophenyl）methyl chloride（TNPMCl）.Firstly,TPM was allowed to react with mixed acid to give tris（4-nitrophenyl）methane（TNPM）.Secondly,TNPM was oxidized by CrO3/acetic acid to give tris（4-nitrophenyl）methanol（TNPMO）.Finally,TNPMCl was obtained by the reaction of TNPMO with acetyl chloride.The compounds were determined by nuclear magnetic resonance spectrometry and Fourier transform infrared spectrometry.

关 键 词：三(4-硝基苯基)甲醇 三(4-硝基苯基)氯甲烷 三(4-硝基苯基)甲烷 三苯甲烷 合成 表征 

分 类 号：O625.14[理学—有机化学]