含酰胺和席夫碱单元的硫杂杯[4]芳烃衍生物的合成与配合性能  

Syntheses and complexation property of thiacalix[4]arene derivatives containing amides and schiff-base units

作　　者：赵夏[1] 杨发福[2] 

机构地区：[1]银川能源学院石油化工系,银川750105 [2]福建师范大学化学与材料学院,福州350007

出　　处：《化工新型材料》2014年第7期142-143,146,共3页New Chemical Materials

基　　金：国家自然科学基金(20402002);宁夏高等学校科学研究资助项目;银川能源学院科学研究资助项目(2013-KY-Z-05)

摘　　要：使用硫杂杯[4]芳烃的四乙酸乙酯衍生物1与过量水合肼反应,生成中间产物硫杂杯[4]芳烃四酰肼衍生物2,然后进一步与相应的芳醛反应,高产率地合成了3个新型的含酰胺和席夫碱单元的杯[4]芳烃衍生物3a-3c,所合成化合物的结构经1H-NMR,ESI-MS和元素分析等证实。又通过阳离子萃取实验证明,新型硫杂杯[4]芳烃衍生物比含有相似官能团的杯芳烃衍生物具有更强的软金属离子配合性能。Thiacalix[4]arene hydrazides derivative 2 was obtained by the reaction of thiacalix[4]arene tetra-ethylae- etates with hydrazine hydrate. Treatment of compound 2 with corresponding aldehydes, three novel Thiaealix[4]arene deriv atives 3a-3c containing amides and schiff-base units were synthesized in high yields. The extraction experiments showed that new thiacalix[4]arene derivatives exhibited higher complexation abilities than calix[4]arene derivatives.

关 键 词：硫杂杯[4]芳烃 合成 席夫碱 配合 

分 类 号：O621.2[理学—有机化学]