稻壳炭基二氧化硅的提取及表征  

Extraction and characterization of SiO_2 from rice-husk-char

作　　者：顾洁[1] 刘斌[2] 方放[2] 马中青[1] 张齐生[1] 周建斌[1] 

机构地区：[1]南京林业大学竹材工程研究中心,江苏南京210037 [2]南京林业大学化学工程学院,江苏南京210037

出　　处：《化工学报》2014年第8期3277-3282,共6页CIESC Journal

基　　金：林业公益性行业科研专项项目(201304611);国家科技支撑计划项目(2012BAD30BOO);国家重点基础研究发展计划项目(2010CB732205);高校优势学科建设工程项目~~

摘　　要：以气化副产物稻壳炭为原料,以K2CO3作为提取剂制取SiO2产品,考察了提取工艺和陈化工艺对产品得率的影响。得到最优工艺:K2CO3质量分数为20%,浸渍比为3.0,煮溶时间为3.5 h,陈化温度为3℃,陈化时间为3 h。最优工艺下制备的SiO2得率为25.89%,酸处理后纯度为97.02%。采用场发射扫描电子显微镜(SEM)、X射线能谱仪(EDX)、X射线衍射仪(XRD)等对产品的性能进行了表征。The objective of this study is to develop a simple and green procedure for preparing SiO2 from rice husk char. The raw material, rice husk char from downdraft fixed bed gasification was used to extract SiO2 by adding K2CO3. To find the influence of extraction and aging conditions on SiO2 yield, the experiments were conducted. The results showed that the optimum conditions were as follows：the impregnation ratio of K2CO3 solution （mass fraction of 20%） to rice husk char was 3.0, the extraction time 3.5 h. The temperature and time of aging was 3℃and 3 h, respectively. At these conditions, SiO2 yield was 25.89% and purity 97.02% after acid treatment. The structure and property of SiO2 were analyzed using SEM, EDX, and XRD. The results indicated that it could be a practical way for the high efficiency, environmental-friendly and resource utilization of rice husk char.

关 键 词：稻壳炭 碳酸钾 提取 二氧化硅 回收 

分 类 号：TQ127.2[化学工程—无机化工]