Influence of Gd doping on the absolute quantum efficiency and lifetime of Eu_xGd_(1-x)(TTA)_3 phens  

作　　者：Ting-Ting Dai Lei Liu Dong-Liang Tao Shi-Gang Li HongZhang Yu-Min Cui Yong-Zhong Wang Ji-Tang Chen Kun Zhang Wen-Zhong Sun Xiao-Yun Zhao gel Liu 

机构地区：[1]College of Chemistry and Chemical Industry, Fuyang Normal College, Fuyang 236041, China [2]Anhui Provincial Key Laboratory for Degradation and Monitoring of Pollution of the Environment, Fuyang 236041, China [3]School of Physics and Electronic Science, Fuyang Normal College, Fuyang 236041, China

出　　处：《Chinese Chemical Letters》2014年第6期892-896,共5页中国化学快报（英文版）

基　　金：supported by the National Natural Science Foundation of China(No.50973003);Anhui Science and TechnologyProgram(Nos.KJ2012B135,KJ2012A217,KJ2012B136,KJ2011A210, 1301042112);Natural Science Foundation of Fuyang Normal College (Nos.2011HJJC02ZD,2011HJJC01ZD,2011HJJC04YB,2010FSKJ01ZD, 2013FSKJ03ZD);Incubator Fund of Scientific and Technological achievements of Fuyang Normal College(Nos.2013KJFH03, 2013KJFH01)

摘　　要：Absolute quantum yield （Ф） is one of the most important parameters to evaluate the potential of novel materials. Lanthanide complexes EuxGd1-x（TTA）3phens are synthesized with the ratio of Gd3＋ dopant concentration ranging from 10% to 90% to improve the absolute quantum yield. EuxGd1-x（TTA）3phens possess similar infrared and ultraviolet spectra, showing that they have similar molecular structures. The absolute emission quantum yields of EuxGd1-x（TTA）3phens are determined using a fluoromax-4 spectrofluorometer equipped with an integrating sphere. The fluorescence lifetimes of the EuxGd1-x（TTA）3phens are measured in the same experiment. It was found that both absolute quantum yields and fluorescence lifetimes of EuxGd1-x（TTA）3phens are of quasi-periodic variation with the change of the Gd3. dopant concentrations. The absolute quantum efficiency and fluorescence lifetime vary with respect to the Gd content in an opposite fashion, indicating that the rate of energy absorption by the EuxGd1-x（TTA）3phens and the conversion to light energy is critical for the absolute quantum efficiency. The radiative rate constant Kr and non-radiative rate constant Knr are calculated. The dependence of Kr and Knr on the Gd3＋ dopant concentrations is very similar to that of absolute quantum efficiency. The radiation rate constant Kr and absolute quantum efficiency have a linear relationship.Absolute quantum yield （Ф） is one of the most important parameters to evaluate the potential of novel materials. Lanthanide complexes EuxGd1-x（TTA）3phens are synthesized with the ratio of Gd3＋ dopant concentration ranging from 10% to 90% to improve the absolute quantum yield. EuxGd1-x（TTA）3phens possess similar infrared and ultraviolet spectra, showing that they have similar molecular structures. The absolute emission quantum yields of EuxGd1-x（TTA）3phens are determined using a fluoromax-4 spectrofluorometer equipped with an integrating sphere. The fluorescence lifetimes of the EuxGd1-x（TTA）3phens are measured in the same experiment. It was found that both absolute quantum yields and fluorescence lifetimes of EuxGd1-x（TTA）3phens are of quasi-periodic variation with the change of the Gd3. dopant concentrations. The absolute quantum efficiency and fluorescence lifetime vary with respect to the Gd content in an opposite fashion, indicating that the rate of energy absorption by the EuxGd1-x（TTA）3phens and the conversion to light energy is critical for the absolute quantum efficiency. The radiative rate constant Kr and non-radiative rate constant Knr are calculated. The dependence of Kr and Knr on the Gd3＋ dopant concentrations is very similar to that of absolute quantum efficiency. The radiation rate constant Kr and absolute quantum efficiency have a linear relationship.

关 键 词：JEuropium complexes Gd doping Absolute quantum yield Fluorescent lifetime 

分 类 号：O614.33[理学—无机化学]