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出 处:《节水灌溉》2014年第7期54-57,共4页Water Saving Irrigation
基 金:国家自然科学基金(41203050);中国地调局地质调查项目(1212011140036)
摘 要:主要研究草炭土在修复地下水石油烃过程中水化学因子的变化规律,实验选取Fe3+、Mn2+、SO4^2-、Ca2、Mg2+、NH4+、HPO4^2-、NO3-离子进行相关研究,实验结果表明草炭土对于水化学因子有一定的改变作用,对Ca2’的去除率稍低在58.77%~66.50%之间,Mn2+、NH+、Mg2+、NO3-的去除率均大于80%,而SO4^2-、Fe3+、HPO4^2-几乎被全部去除,去除率均大于97%。SO4^2-、NH4+、NO3-对草炭土吸附石油烃具有促进作用,Ca2+对草炭土吸附石油烃具有抑制作用,较低浓度的HPO4^2-不利于草炭土去除石油烃,Fe3+、Mn2+、Mg2+对草炭土吸附石油烃影响不明显,8种离子对草炭土吸附石油烃的影响随浓度改变。This paper mainly studies the variation law of hydro-chemical factors during repair process of the peat soil for petroleum hydrocarbons in groundwater. In the experiments, the elements of Fe3+、Mn2+、SO4^2-、Ca2、Mg2+、NH4+、HPO4^2-、 , and NO3- are chosen to conduct the research. The results show that the peat soil has a certain effect on the changes of water chemical faetors; the removal rate of Ca2+ is between 58. 77% to 66. 50%, that of Mn2+ , NH4+ ,Mg2+ , NO3- is greater than 80%, while Fe3+ , SO4^2-, HPO4^2- are almost completely removed and the removal rates are more than 97%. The SO4^2- ,NH+ , and NO2 have promotion effect on the adsorption of the peat soil for petroleum hydrocarbons, while Ca2+ has the inhibition effect on the adsorption of the peat soil for petroleum hydroearbons; HPO4^2- with lower concentration is not conducive for the removal of petroleum hydrocarbons, the Mn2+ , Mg2+ have no significant effects on it. The effects of the eight kinds of ions on the adsorption of the peat soil for petroleum hydrocarbons change with the concentration.
分 类 号:X523[环境科学与工程—环境工程]
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