9,10-二(β-萘基)蒽-2-硼酸的合成研究  

Synthesis of 9,10-Di( β-naphthyl) anthracene-2-boronic Acid

作　　者：祝艳龙 徐茂梁[1] 姜菡雨[1] 安永[1] 王歌扬[1] 

机构地区：[1]西安近代化学研究所,陕西西安710065

出　　处：《化学试剂》2014年第8期693-695,754,共4页Chemical Reagents

基　　金：西安市经开区科技创新项目(JKZD110532)

摘　　要：以2-溴-9,10-二(β-萘基)蒽为原料,在低温条件下得到9,10-二(β-萘基)蒽-2-硼酸,并通过核磁共振、红外光谱分析、元素分析、质谱分析对其结构进行了确认和表征。并探讨了不同反应条件对收率的影响,确定了反应的最佳条件为:在-78℃下,以叔丁基锂作为锂试剂,以物质的量比为n(卤代芳烃)∶n(锂试剂)∶n(硼酸酯)=1∶5∶6,分别滴加叔丁基锂、硼酸三异丙酯,收率可达76.80%。9, 10-Di （β-naphthyl） anthracene-2-boronic acid was synthesized by using 2-bromo-9, 10-di （β-naphthyl） anthracene as the starting material under thelow temperature, and the structure was confirmed by ^1HNMR, ^13CNMR, IR spectroscopy,elemental analysis and mass spectrometry. The effects on the reaction yield by conditions and different sub- stituents were discussed, the optimal reaction condition was obtained as follows： -78 ℃, using t-butyllithium as the lithium reagent, the molar ratio of halogenated aromatics： lithium reagents： borate = 1：5： 6,t-butyllithium and triisopropyl borate was added ,respectively. The yield was up to 76. 80%.

关 键 词：蒽衍生物 芳基硼酸 合成 

分 类 号：TQ242.4[化学工程—有机化工]