Effect of Schiff base as corrosion inhibitor on AZ31 magnesium alloy in hydrochloric acid solution  

席夫碱作为缓蚀剂对盐酸溶液中AZ31镁合金的影响(英文)

作　　者：S.THIRUGNANASELVI S.KUTTIRANI Amali Roseline EMELDA 

机构地区：[1]Department of Chemistry,Sri Ramanujar Engineering College [2]Department of Chemistry,BS Abdur Rahman University

出　　处：《Transactions of Nonferrous Metals Society of China》2014年第6期1969-1977,共9页中国有色金属学报（英文版）

摘　　要：Schiff base derived from the condensation reaction of analar grade 1-amino-2-naphthol 4-sulphonic acid with cinnamaldehyde was prepared under microwave condition.The Schiff base was analysed by infrared spectroscopy.This Schiff base as a corrosion inhibitor of AZ31 magnesium alloy in 0.05 mol/L HCl solution was studied.The inhibition effect of the Schifif base compound（4Z）-4-（3-phenyl allylidene amino）-3-hydroxy naphthalene-1-sulfonic acid（AC） on AZ31 magnesium alloy corrosion was studied using mass loss,potentiodynamic polarization technique,electrochemical impedance spectroscopy methods.The potentiodynamic polarization curve shows that Schiff base AC inhibits both anodic and cathodic reactions at all concentration,which indicates it is a mixed type inhibitor.EIS results indicate that as the additive concentration is increased,the polarization resistance increases whereas double-layer capacitance decreases.The adsorption of AC on the AZ31 magnesium alloy surface in 0.05 mol/L HCl obeys the Langmuir adsorption isotherm.在微波条件下,通过高纯度1-氨基-2萘酚4-磺酸与肉桂醛的缩合反应制备席夫碱(4Z)-4-(3-苯基烯丙叉氨基)-3-羟基萘-1-磺酸(AC)。采用红外光谱对制备的席夫碱进行分析。研究席夫碱作为缓蚀剂对AZ31镁合金在0.05mol/L盐酸中的缓蚀作用。通过质量损失法、动电位极化法和电化学交流阻抗谱(EIS)研究席夫碱化合物在AZ31镁合金腐蚀过程中的抑制作用。动电位极化曲线表明:席夫碱在所有浓度下能抑制阳极和阴极反应,是一种混合型缓蚀剂。EIS结果表明:随着添加剂浓度的增加,极化电阻增加而双电层电容减少。在0.05 mol/L盐酸中,席夫碱AC对AZ31镁合金表面的吸附符合Langmuir吸附等温式。

关 键 词：Schiff base AZ31 magnesium alloy corrosion inhibitor potentiodynamic polarization electrochemical impedance spectroscopy 

分 类 号：TG174.42[金属学及工艺—金属表面处理] TG146.22[金属学及工艺—金属学]