铅-3-噻吩甲酸二元配合物的合成与表征  

Synthesis and Characterization of Lead-3-thiophene Formate Binary Complexes

作　　者：宋彦佩 刁开盛[1,2] 肖汉[1] 杨桂柳 李贺[1] 

机构地区：[1]广西民族大学化学化工学院,广西南宁530006 [2]广西民族大学广西林产化学与工程重点实验室,广西南宁530006

出　　处：《广西民族大学学报（自然科学版）》2014年第3期90-93,共4页Journal of Guangxi Minzu University ：Natural Science Edition

基　　金：广西自然科学基金项目(2013GXNSFAA019091)

摘　　要：采用3-噻吩甲酸及1,10菲罗琳以水热合成的方法合成了一种新的硝酸铅配合物Pb2(TPA)2(PHRL)2(NO3).H2O,对其用单晶射线衍射分析,X单晶衍射结果表明:配合物处于单斜晶系P2(1)/n空间群.元素分析,红外光谱,紫外光谱及熔点测试进行了表征.A complex C34 H26 Pb2 N6 O12 S2 has been synthesized by the reaction of 3-thiophenezoic acid 1,10-Phenanthroline monohydrate and lead nitrate under hydrothermal conditions. Its structure was con firmed by X-ray diffraction analysis in its single crystal. The crystal of the title complex belongs to monoclin ic system P2 （1）/n space group. Still, it was characterized by elemental analysis, spectral method（IR） uv a nalysis and melting point test.

关 键 词：3-噻吩甲酸 铅 双核 晶体结构 

分 类 号：O641[理学—物理化学]