樟脑酸构筑的铜、钴配合物的合成、晶体结构及电化学性质  

Synthesis,Crystal Structure and Electrochemical Properties of Copper and Cobalt Complexes Constructed from(1S,3R)-Camphoric Acid

作　　者：黄妙龄 

机构地区：[1]泉州师范学化学与生命科学学院,泉州362000

出　　处：《人工晶体学报》2014年第7期1872-1878,共7页Journal of Synthetic Crystals

基　　金：国家自然科学基金(21353001);结构化学国家重点实验室科学基金(20120016);福建省教育厅基金(JK2011042;JK2012039)

摘　　要：分别采用普通溶液法和溶剂热法合成了两个以樟脑酸(D-H2Cam)为主配体的配合物。X射线单晶衍射分析结果表明:配合物[Cu(D-HCam)2(phen)]·2H2O(1)为单核配合物,四方晶系,P41212空间群,中心铜离子处于变形的四边形的配位环境;配合物{[Co(Hcam)2(4,4'-bipy)(H2O)2]·0.4(H2O)2·3.2H2O}n(2)为一维分子链,正交晶系,C2221空间群,有六个原子在钴原子周围形成一个稍变形的八面体配位环境。同时对两个配合物的热稳定性和电化学性质进行了研究。The two complexes,[Cu（D-HCam）2（phen） ]·2H2O（1） and { [Co（Hcam）2（4,4’-bipy）（H2O）2]·0. 4（H2O）2·3. 2H2 O }n（2）,were synthesized by common solution method and solvothermal method,and their crystal structure were determined by single crystal X-ray diffraction analysis. The complex 1 is a mononuclear-molecule. The crystal is of tetragonal system,with space group P41212. The coordination polyhedron of Cu2 ＋is distorted quadrangle. While,the complex 2 is a onedimensional chain molecule,the crystal is of orthorhombic system,with space group C2221. The coordination polyhedron of Co2 ＋is slightly distorted octahedron with six atoms. On the other hand,TG analysis and the cyclic voltammetric behavior of the two complexes were investigated.

关 键 词：铜配合物 钴配合物 (1S 3R)樟脑酸 邻菲罗啉 4 4-联吡啶 晶体结构 电化学性质 

分 类 号：O614.331[理学—无机化学]