苯乙烯环氧化制环氧苯乙烷的催化剂研究进展  

Research evolution of catalysts on epoxyethylbenzene production through epoxidation of styrene

作　　者：高晓红[1] 冯辉霞[2] 

机构地区：[1]兰州石化职业技术学院应用化学工程系,甘肃兰州730060 [2]兰州理工大学石油化工学院,甘肃兰州730060

出　　处：《应用化工》2014年第8期1489-1492,共4页Applied Chemical Industry

基　　金：国家自然科学基金(51063003);国家科技部"科技人员服务企业行动项目"(2009GJG10041);甘肃省高校基本科研业务费(1105ZTC136)

摘　　要：介绍苯乙烯环氧化制取环氧苯乙烷的几种催化体系,重点叙述了Mn、Ag、Ti、Co、Fe等负载型催化剂,同时介绍了具有巨大潜力的席夫碱金属配合物催化剂的前景。Styrene oxide is an important intermediate for organic synthesis,pharmacy and toiletries. In re-cent years,the catalyst used for synthesis of styrene oxide are mainly molecular sieve and metal complex catalyst,research more and get a better research results. This paper describes several kinds of catalytic systems used for preparation of styrene oxide. Meanwhile,the paper especially focuses on presenting sever-al supported metal（Mn,Ag,Ti,Co,Fe）catalysts. Besides,the paper also elucidates the perspective of Schiff base metal complexes with huge development potential.

关 键 词：苯乙烯 配合物 固载催化剂 席夫碱金属配合物 

分 类 号：TQ032.41[化学工程]