欧盟玩具安全新指令化学要求及测试方法综述  

Review on Chemical Requirements and Related Testing Methods of the New EU Toy Safety Directive

作　　者：黄理纳[1] 方晗[1] 蚁乐洲[1] 郑建国[1] 

机构地区：[1]广东出入境检验检疫局检验检疫技术中心,广东广州510623

出　　处：《分析测试学报》2014年第8期971-978,共8页Journal of Instrumental Analysis

基　　金：广东省科技计划项目(2012B050600027);质检公益性行业科研专项基金(2012104020)

摘　　要：2013年开始实施的欧盟玩具安全指令对化学物质的检测要求更加严格,限制迁移元素从8种增加到包含三价铬、六价铬和有机锡的19种,增加了对N-亚硝胺类物质的迁移量和致敏性芳香剂的限制;限量降低,铅、镉、六价格、有机锡限量分别只有3.4,0.5,0.005,0.2 mg/kg,传统玩具检测使用的ICP-OES和GC-MS已无法满足六价铬、有机锡、亚硝胺、芳香剂的检测要求。该文简述了指令的化学相关要求以及相应的检测方法,重点介绍了六价铬和有机锡检测方法的技术进展和技术难点。The EU Toy Safety Directive which came into force in 2013 has substaintially increased requirements on chemical substances.Restricted migration elements have been increased from 8 to 19elements,which include trivalent chromium,hexavalent chromium and organotin.Restricted migration amount of N-nitrosamines and restriction of allergenic fragrances have been added.The limited amounts of lead,cadmium,hexavalent chromium,organotin have been decreased to 3.4,0.5,0.005,0.2 mg/kg respectively,and traditional toy testing methods such as inductively coupled plasma-optical emission spectrometry and gas chromatography-mass spectrometry cannot satisfy the testing requirements of hexavalent chromium,organotin,N-nitrosamines and fragrances.This paper has briefly described the chemical requirements of TSD and corresponding testing methods,highlighted the technical progress and difficulties of testing methods of hexavalent chromium and organotin.

关 键 词：玩具 欧盟玩具安全指令 六价铬 有机锡 亚硝胺 

分 类 号：O657.63[理学—分析化学] G614[理学—化学]