C_(60)亚甲基衍生物的制备与表征  

Preparation and characterization of methanofullerene

作　　者：卢骏安[1] 王洪晶[1] 王越[1] 韩爱鸿[1] 

机构地区：[1]沈阳师范大学化学与生命科学学院,辽宁沈阳110034

出　　处：《化学研究与应用》2014年第8期1330-1333,共4页Chemical Research and Application

摘　　要：对富勒烯C60进行化学改性,合成的材料适用于聚合物太阳能电池的受体材料。以对甲氧基苯甲醇为起始原料,再经过几步酯化反应,生成不对称丙二酸双酯,最后利用Bingel反应制备出一种C60富勒烯衍生物,作为潜在的光电材料,其光电特性经CV和UV表征。通过经验公式计算其LUMO能级比PCBM高出0.13eV,是一种潜在的受体材料。The chemical modification of fullerenes C60 was reported. The synthesized compounds were employed as an acceptor for organic solar cell. p-methoxybenzyl alcohol was used as starting material. Next,the asymmetric malonic acid di-ester was prepared through esterification,final a fullerene derivative was prepared by Bingel reaction. As a potential photoelectric material,its photoe-lectric properties were characterized by cyclic-voltammetry（CV）and Ultraviolet spectrophotometry（UV）. It’s LUMO energy level was higher than the level of PCBM by 0. 13eV,this was a potential photoelectric material.

关 键 词：富勒烯 三异丙基氯硅烷 丙二酸亚异丙酯 光电材料 

分 类 号：O623.5[理学—有机化学]