Properties of La_(0.9)Sr_(0.1)MnO_3 and tourmaline compound catalytic materials for methane combustion  

作　　者：薛刚 赵颖 梁金生 苑砚坤 王赛飞 陈丹 

机构地区：[1]Institute of Power Source and Ecomaterials Science, School of Materials Science and Engineering, Hebei University of Technology

出　　处：《Journal of Rare Earths》2014年第9期837-841,共5页稀土学报（英文版）

基　　金：Project supported by National High Technology Research and Development Program of China(863 Program)(2011AA03A406);the Natural Science Foundation of Hebei Province of China(E2014202194)

摘　　要：A novel catalytic material Lao.9Sr0.1MnO3 and tourmaline compound catalytic material was synthesized in the base of traditional catalytic material La0.9Sr0.1MnO3 which exhibited excellent catalytic activity for methane combustion. Different contents of toumaaline were added to give a series ofLa0.9Sr0.1MnO3 and tourmaline catalytic material through a sol-gel method. Samples above were characterized and analyzed by means of X-ray diffraction （XRD）, scanning electron microscopy （SEM）, Brunauer-Emmett-Teller method （BET）, temperaalre programmed reduction （TPR）, catalytic activity test and contact angle test. The as-prepared sample with 2% （m/m） tourmaline showed good homogeneity surface morphology and displayed the optimal catalytic activity. The light-off temperature reduced by 10 ℃ and the T90 decreased by 15 ℃. In addition, the mechanism of the reinforcement of catalytic activity was explored.A novel catalytic material Lao.9Sr0.1MnO3 and tourmaline compound catalytic material was synthesized in the base of traditional catalytic material La0.9Sr0.1MnO3 which exhibited excellent catalytic activity for methane combustion. Different contents of toumaaline were added to give a series ofLa0.9Sr0.1MnO3 and tourmaline catalytic material through a sol-gel method. Samples above were characterized and analyzed by means of X-ray diffraction （XRD）, scanning electron microscopy （SEM）, Brunauer-Emmett-Teller method （BET）, temperaalre programmed reduction （TPR）, catalytic activity test and contact angle test. The as-prepared sample with 2% （m/m） tourmaline showed good homogeneity surface morphology and displayed the optimal catalytic activity. The light-off temperature reduced by 10 ℃ and the T90 decreased by 15 ℃. In addition, the mechanism of the reinforcement of catalytic activity was explored.

关 键 词：methane combustion PEROVSKITE TOURMALINE sol-gel method CATALYTIC rare earths 

分 类 号：O614.332[理学—无机化学] O643.36[理学—化学]