CL-14的热行为及与CMDB推进剂的相互作用  

Thermal Behavior of CL-14 and Interaction of CL-14 with CMDB Propellant

作　　者：付小龙[1] 樊学忠[1] 霍欢[1] 刘小刚[1] 王晗[1] 王伯周[1] 

机构地区：[1]西安近代化学研究所,西安710065

出　　处：《科学技术与工程》2014年第24期169-173,共5页Science Technology and Engineering

摘　　要：采用差示扫描量热法(DSC)研究了5,7-二氨基-4,6-二硝基苯并氧化呋咱(CL-14)的热行为及CL-14与奥克托今(HMX)、黑索今(RDX)、硝化甘油(NG)和硝化棉(NC)的相互作用;同时,采用真空安定性法(VST)研究了吉钠(DINA)、炭黑(CB)、三氧化二铝(Al2O3)、2,4-二羟基苯甲酸铜(β-Cu)、NTO铜(NTO-Cu)、邻苯二甲酸铅(φ-Pb)和NTO铅(NTO-Pb)的相互作用。结果表明,CL-14与HMX、RDX、NG和NC等推进剂主要组分之间无明显相互作用,且与吉钠(DINA)、炭黑(CB)、三氧化二铝(Al2O3)、2,4-二羟基苯甲酸铜(β-Cu)、NTO铜(NTO-Cu)和NTO铅(NTO-Pb)的相互作用较小。CL-14与CMDB推进剂药浆无燃烧、爆炸等剧烈的化学作用,可在CMDB推进剂中应用。The thermal behavior of 5,7-diamino-4,6-dinitro Benzenfuroxan （CL-14） was studied.The interaction of CL-14 with main ingredient of CMDB propellants including HMX,RDX,NG and NC were studied by DSC.The interaction of CL-14 with DINA,CB,A12O3,β-Cu,NTO-Cu,（o）-Pb and NTO-Pb were studied by VST.It was found that there are no obvious interactions of CL-14 with HMX,RDX,NG and NC by DSC,and the interactions between CL-14 and DINA,CB,Al2O3,β-Cu,NTO-Cu,（o）-Pb and NTO-Pb are weak.There is no strong chemical reaction such as combustion and explosion between CL-14 and CMDB propellant mixture system.It can be concluded from the results that CL-14 was used in CMDB propellant.

关 键 词：物理化学 相互作用 5 7-二氨基-4 6-二硝基苯并氧化呋咱(CL-14) DSC VST 

分 类 号：O625.75[理学—有机化学]