铜离子配位调控的TICT荧光化合物的双重荧光发射（英文）  

Copper(Ⅱ) Ion Coordination-Controlled Twisted Intramolecular Charge Transfer Dual Fluorescence Emission

作　　者：张静丽[1] 范伟贞[1] 闫素婷[1] 林丽榕[1] 黄荣彬[1] 

机构地区：[1]厦门大学化学化工学院,厦门361005

出　　处：《无机化学学报》2014年第9期2181-2188,共8页Chinese Journal of Inorganic Chemistry

基　　金：国家自然科学基金(No.21271150);国家基础科学人才培养基金(No.J1310024)资助项目

摘　　要：设计合成了2个分子内扭转电荷转移(TICT)荧光体(1和2),铜离子的配位作用可开关其双重荧光发射。2在乙腈/水溶液(1∶1,V/V)中的双重荧光发射随着铜离子的加入以类似电子转移机制"开-关"形式猝灭,而1在铜离子与其计量比为1之内的乙腈/水溶液(1∶1,V/V)中,其双重荧光发射随着铜离子的加入逐渐猝灭;在计量比之后其长波长的TICT荧光发射随着铜离子的加入逐渐增强。即1的TICT荧光发射以"开-关-开"的机制被铜离子诱导。同时还获得了铜离子与1形成的配合物的晶体结构以及配合物的荧光性质。1H NMR波谱滴定实验表明荧光体的电荷转移程度是影响TICT发射的主要因素,1是一个新的且其TICT发射可以被铜离子调制为"开-关-开"的TICT荧光体。Two twisted intramolecular charge transfer（TICT） fluorophores（1 and 2） were designed and synthesized to control the dual fluorescence emission by Cu2 ＋coordination. The dual fluorescence of 2 is quenched upon the addition of Cu^2＋ions in an ＂on-off＂ process similar to PET inhibition. The dual fluorescence of 1 exhibits emission quenching initially and then long-wavelength band（TICT band） emission enhancement with ＂on-off-on＂ signalling behaviour. The crystal structure of the Cu2＋complex with 1 was also obtained, and its fluorescence properties were reported.1H NMR spectral titration results indicate that the degree of charge transfer is a crucial factor for the resulting TICT state emission. Fluorophore 1 is a new TICT compound in which TICT emission can be tuned by copper ions with a dramatic change via ＂on-off-on＂ signalling behaviour. CCDC： 899958, Cu^2＋-1.

关 键 词：分子内扭转电荷转移(TICT) 双重荧光 铜离子 配位 “开-关-开” 

分 类 号：O614.121[理学—无机化学]