液相中镍催化剂催化合成气甲烷化的初步研究  

Syngas methanation over nickel catalyst in liquid-phase

作　　者：黄国宝[1,2] 王志青[1] 李庆峰[1] 黄戒介[1] 房倚天[1] 

机构地区：[1]中国科学院山西煤炭化学研究所煤转化国家重点实验室,山西太原030001 [2]中国科学院大学,北京100049

出　　处：《燃料化学学报》2014年第8期952-957,共6页Journal of Fuel Chemistry and Technology

基　　金：国家自然科学基金青年科学基金(21106173);中国科学院战略性先导科技专项(XDA07050100);山西省青年科技研究基金(2013021007-2);中国科学院山西煤炭化学研究所青年人才项目(2011SQNRC01)

摘　　要：采用液相还原法制备非负载型镍催化剂,将非负载型镍催化剂分散在液相供氢溶剂十氢萘中,催化合成气甲烷化反应。在高压反应釜内,考察了反应温度、物质的量比等操作条件下,镍催化剂催化合成气甲烷化反应的反应活性。并对催化剂进行XRD、SEM、H2-TPR表征分析。研究结果表明,在330℃、催化剂用量为2%时,产品气中甲烷含量可达89.39%,CO和H2的转化率分别为94.56%和92.60%；催化剂用量为4%时,产品气中甲烷含量可高达94.26%,CO的转化率可达到99%以上。合成气甲烷化反应的最佳操作温度为330℃,H2/CO物质的量比最佳为2.20~2.67。Unsupported metal nickel catalysts were prepared by liquid phase reduction method. The catalytic performance of the catalysts for syngas methanation were conducted in an autoclave using decalin as the hydrogen donor solvent at different operation conditions, such as temperature, mol ratio of H2/CO in feed gas. And the catalyst characterizations were conducted by means of XRD, SEM, H2-TPR. The results showed that the content of CH4 in the product gas was 89. 39% when 2% catalyst was used at 330℃, and the corresponding conversions of CO and H2 were 94. 56% and 92. 60%, respectively. When 4% catalyst was used, the CO conversion was further improved to more than 99% while the content of CH4 in the product gas exceeded 94. 26%. The best operation temperature of syngas methanation in liquid phase was 330 ℃and the optimum range of H2/CO mol ratio in feed was 2 . 20～2 . 67 .

关 键 词：合成气甲烷化 十氢萘 供氢溶剂 镍催化剂 

分 类 号：TQ032[化学工程]